Electrochemical CO2 reduction to formate is a promising approach store renewable electricity and utilize CO2. Tin oxide catalysts are efficient for this process, while the mechanisms underneath, especially existence role of oxidized tin species under electroreduction conditions remain unclear. In work, we provide strong evidence on presence both SnO2 Sn during via in situ surface-enhanced Raman...

The structures and physicochemical properties of surface-stabilizing molecules play a critical role in defining the properties, interactions, functionality hybrid nanomaterials such as monolayer-stabilized nanoparticles. Concurrently, distinct surface-bound interfacial environment imposes very specific conditions on molecular reactivity behavior this setting. Our ability to probe nanoscale syst...

The oxygen reduction reaction (ORR) in 0.1 M NaOH on platinum single crystal electrodes has been studied using hanging meniscus rotating disk electrode configuration. Basal planes and stepped surfaces with (111) and (100) terraces have been employed. The results indicate that the Pt(111) electrode has the highest electrocatalytic activity among all the studied surfaces. The addition of steps on...

background and objective: alzheimer’s disease (ad) is a multifactorial disease with debilitating consequences and few therapeutic strategies exist for it. with regard to antioxidant capacity and anti-β-amyloid polymerization potential of ellagic acid, this study was conducted to evaluate the effect of this substance on enhanced acetylcholinesterase reactivity in an experimental model of alzheim...

background and objectives: brucella melitensis infection is still a major health problem for human and cattle in developing countries and the middle east. materials and methods: in this study, in order to screen immunogenic candidate antigens for the development of a brucella subunit vaccine, a cytoplasmic protein (dnak) and an outer membrane protein (omp31) of b. melitensis were cloned, expres...

background: several studies reported the clinical features of ige-mediated hypersensitivity after ingestion of melon. melon allergy is a common ige-mediated fruit allergy in iran. this prompted us to investigate immunochemical and molecular properties of the major allergen in melon fruit, to compare the ige-binding capacity of the natural protein with the recombinant allergen, and to determine ...

Model catalyst surfaces, consisting of vapordeposited metal nanoparticles supported on a planar oxide support, can help to link reactivity studies on well-defined single crystal surfaces with those conducted on high-surface area supported catalysts. When coupled with near atmospheric pressure kinetic and spectroscopic techniques, these well-defined model catalyst surfaces represent a useful app...

Remediation of sites contaminated by toxic chlorinated organic compounds by using nanoscale iron particles (NIP) has received great attention owing to their high reactivity resulting from small size and large reactive surface area. However, adequate delivery of NIP into the contaminated zones for in situ remediation applications is difficult because of NIP agglomeration and sedimentation. Diffe...