One of the methods of disposal of sewage sludge, which is based on its fertilizing properties, is its use in nature, e.g. in farming (if all the permissible standards are met). However, the sludge used for soil fertilization might also contain heavy metals which cause soil contamination and are accumulated in plants. The effect of application of organic fertilizers on soil reaction and other pr...

A [2+3] organic cage compound based on the condensation reaction of 1,3,5-tri(4-formylphenyl)benzene with 1,5-pentanediamine was synthesized. The resulting porous molecular crystal demonstrates selective adsorption of hydrogen and carbon dioxide over nitrogen. As for porous polymer membranes, a trade-off between sorption capacity and selectivity is observed for materials in this class.

Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol-yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.

Hybrid sorbents and biosorbents were synthesized via chemical and biological treatment of active carbon by simple and direct redox reaction followed by surface loading of baker's yeast. Surface functionality and morphology of chemically and biologically modified sorbents and biosorbents were studied by Fourier Transform Infrared analysis and scanning electron microscope imaging. Hybrid carbonac...

The sorption and desorption of Pb on RuO2.xH2O were examined kinetically and thermodynamically via spectroscopic and macroscopic investigations. X-ray absorption spectroscopy (XAS) was employed to determine the sorption mechanism with regard to identity and interaction of nearest atomic neighbors, bond distances (R), and coordination numbers (N). The kinetics of the Pb-Ru-oxide sorption reactio...

Catalytic steam reforming of glycerol for H(2) production has been evaluated experimentally in a continuous flow fixed-bed reactor. The experiments were carried out under atmospheric pressure within a temperature range of 400-700 degrees C. A commercial Ni-based catalyst and a dolomite sorbent were used for the steam reforming reactions and in situ CO(2) removal. The product gases were measured...

The direct deposition of polyethyleneimine (PEI), a weak polycation with large content amino groups, onto sand fractions different sizes (F70, F100, F200, and F355), resulted in versatile core-shell sorbents for water cleaning. Herein, PEI the polyanion poly(acrylic acid) (PAA) were directly precipitated as an nonstoichiometric polyelectrolyte complex ([PEI]:[PAA] = 2:1) surface followed by cro...