A template-directed method for the synthesis and organization of partially oxidized polypyrrole (PPy) nanoscale arrays within the solvent channels of glutaraldehyde-cross-linked lysozyme single crystals is presented. Macroscopic single crystals of the periodically arranged protein-polymer superstructure are electrically conductive, insoluble in water and organic solvents, and display increased ...

Rubrene, perylene, -quaterthiophene, and tetracene single crystals were grown and placed between indiumtin-oxide and Al electrodes; the current-voltage characteristics of the so-fabricated two-terminal organic devices were measured at ambient conditions under solar simulator illumination. While rubrene single crystals do not exhibit any photovoltaic effect, open-circuit voltages reach values up...

Pure bisthiourea cadmium bromide (BTCB) and 1 mole % L-alanine mixed bisthiourea cadmium bromide (LABTCB) single crystals have been grown by slow evaporation method. The grown crystals have been characterized by single crystal XRD analysis, powder XRD analysis, FTIR analysis, UV-Vis-NIR analysis and SHG studies. XRD analysis confirms the crystalline nature of the materials. The addition of L-al...

We have directly observed the structural evolution of colloidal crystals as a function of increasing ionic strength using confocal scanning laser microscopy. Silica colloids were sedimented onto a glass substrate in deionized water to create large, single domain crystals. The solution ionic strength was then increased by one of three methods of controlled electrolyte addition: (1) direct inject...

Problems of the experimental observation of the birefringence of high energy γ-quanta propagating in single crystals are discussed. 1 Introduction The birefringence of γ-quanta with energies > 1 GeV propagating in single crystals was predicted in [1]. The main process by which γ-quanta are absorbed in single crystals is the electron-positron pair production. The cross section of the process dep...

Relaxor-based ferroelectric single crystals Pb(Mg1/3Nb2/3)O3-PbTiO3 (PMN-PT) have drawn much attention in the ferroelectric field because of their excellent piezoelectric properties and high electromechanical coupling coefficients (d33~2000 pC/N, kt~60%) near the morphotropic phase boundary (MPB). Ternary Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT) single crystals also possess outstan...

We present an all-additive manufacturing method that is performed at mild conditions, for the formation of organic single crystals at specific locations, without any photolithography prefabrication process. The method is composed of two steps; inkjet printing of a confinement frame, composed of a water soluble electrolyte. Then, an organic semiconductor solution is printed within the confinemen...

Single-crystal semiconductors have been at the forefront of scientific interest for more than 70 years, serving as the backbone of electronic devices. Inorganic single crystals are typically grown from a melt using time-consuming and energy-intensive processes. Organic semiconductor single crystals, however, can be grown using solution-based methods at room temperature in air, opening up the po...

Single crystals of Ba9Rh8O24, grown from a molten potassium carbonate flux, crystallize in the spacegroup R3c with lattice parameters of a = 10.0899(4) and c = 41.462(2) A. Magnetic measurements on oriented single crystals reveal the existence of magnetic anisotropy.