Interactions between iron and sulfide in domestic wastewater from a gravity sewer were investigated with particular emphasis on redox cycling of iron and iron sulfide formation. The concentration ranges of iron and total sulfide in the experiments were 0.4-5.4mgFeL(-1) and 0-5.1mgSL(-1), respectively. During anaerobic conditions, iron reduction kinetics were investigated and reduction rates amo...

The silver-activated zinc sulfide, ZnS(Ag), sensor to detect alpha-particles is normally fabricated by means of heat-melting or epoxy mixing spread. However, the fabrication process is very complicated so that it creates high costs and requires special high-tech equipment to manufacture the detector. For this reason, we have developed a new fabrication method which has the advantages of process...

BACKGROUND Formic acid, acetic acid and formaldehyde are important compounds in the indoor environment because of the potential for these acids to degrade calcareous materials (shells, eggs, tiles and geological specimens), paper and corrode or tarnish metals, especially copper and lead. Carbonyl sulfide tarnishes both silver and copper encouraging the formation of surface sulfides. RESULTS C...

Some organisms that survive in environments rich in hydrogen sulfide possess specific metabolic pathways for sulfide oxidation and subsequent use of reducing equivalents in oxidative phosphorylation, a process called chemolithoheterotrophy. This process is dependent on ambient oxygen partial pressure and environmental sulfide exposure. To define accurately the kinetics of sulfide metabolism and...

Accelerating the discovery of new materials is crucial for realizing the vision of need-driven materials development. In the present study we employ an integrated computational and experimental approach to search for new thermoelectric materials. High-throughput first principles calculations of thermoelectric transport coefficients are used to screen sulfide compounds conforming to the boundary...

D iphenyl(l-pyridyl)phosphine sulfide, Ph2pyPS, 1, gives a 1:1 complex (2) with AuCl upon treatm ent with (C4HsS)AuCl. According to an X-ray diffraction analysis, this com ­ pound is isom orphous with the Ph^PS complex. [Ph3PAu]BF4 and 1 give the cationic com plex [Ph;?PAuSPpyPh2]BF4 (3 ) . With two equivalents o f the same reagent the binuclear com plex 4 is generated, in which the metal atoms...

Cadmium-free silver-indium-sulfide (Ag-In-S or AIS) chalcopyrite quantum dots (QDs) as well as their core-shell structures (AIS/ZnS QDs) are being paid significant attention in biomedical applications because of their low toxicity and excellent optical properties. Here we report a simple and safe synthetic system to prepare high quality AIS and AIS/ZnS QDs using thermal decomposition. The synth...

Cyanidation is the main process for gold and silver recovery from its ores. In this study, a process is proposed to recover copper and cyanide from barren solutions from the Merrill-Crowe cementation process with zinc dust. This technology is based on inducing nucleated precipitation of copper and silver in a serpentine reactor, using sodium sulfide as the precipitator, and sulfuric acid for pH...

supergene oxidation-leaching and secondary sulfide enrichment in the sarcheshmeh porphyry cu-mo deposit generated a supergene profile to depths of 20 to 80 meters with oxide ore reserve about 22 mt. @1.08% cu and sulfides ore [email protected]% cu. geochemical distribution and behavior of trace metals associated with cu namely mo, au, and ag in the supergene profile of the sarcheshmeh were po...

Pure and mixed cultures of Methylophaga sulfidovorans and Thiobacillus thioparus T5 were grown in continuous cultures on either dimethyl sulfide, dimethyl sulfide and H(inf2)S, or H(inf2)S and methanol. In pure cultures, M. sulfidovorans showed a lower affinity for sulfide than T. thioparus T5. Mixed cultures, grown on dimethyl sulfide, showed coexistence of both species. M. sulfidovorans fully...