OBJECTIVES This study evaluated the influence of a multi-mode universal adhesive (MUA) containing silane (Single Bond Universal, 3M EPSE) on the bonding of resin cement to lithium disilicate. MATERIALS AND METHODS Thirty IPS e.max CAD specimens (Ivoclar Vivadent) were fabricated. The surfaces were treated as follows: Group A, adhesive that did not contain silane (ANS, Porcelain Bonding Resin,...

Mixed silanes are often used as coupling agents in sizings for glass fibres. A technique has been developed which enables the preferential adsorption of a particular silane onto a model E-glass from a mixed aqueous silane solution to be probed. It is shown that け-Aminopropyltriethoxysilane (APS) is preferentially adsorbed over け-glycidoxypropyltrimethoxysilane (GPS) onto model E-glass fibres. H...

Objectives: To evaluate the micro-tensile repair bond strength between aged and new composite, using silane and adhesives that were cured or left uncured when new composite was placed. Methods: Eighty Filtek Supreme XLT composite blocks and four control blocks were stored in water for two weeks and thermo-cycled. Sandpaper ground, etched and rinsed specimens were divided into two experimental g...

Considerable studies have been performed on the development of optical fiber sensors modified by gold nanoparticles based on the localized surface plasmon resonance (LSPR) technique. The current paper presents a new approach in fiber surface modification technology for biosensors. Star-shaped gold nanoparticles obtained through the seed-mediated solution growth method were found to self-assembl...

We demonstrate a novel route to control attachment of filamentous actin (F-actin) on hydrogel films. By incorporating an amine-terminated silane, the hydrogel surface charge and surface topography are varied. With increasing silane content, F-actin reorients from perpendicular to parallel to the hydrogel surface, ceases to wobble, and forms mainly elongated or cyclic structures. F-Actin coverag...

A study was conducted into the potential of ultrasound as a qualitative and quantitative tool for the Magnetic Density Separator (MDS), where an ultrasound sensor array will operate from inside the MDS ferrofluid. The desired applications of the ultrasound are monitoring of polyolefin particles in flow during the separation process, and performing throughput measurements and quality inspection....

We describe a method to pattern arbitrary-shaped silane self-assembled monolayers (SAMs) with nm scale resolution using DNA nanostructures as templates. The DNA nanostructures assembled on a silicon substrate act as a soft-mask to negatively pattern SAMs. Mixed SAMs can be prepared by back filling the negative tone patterns with a different silane.

A slight excess of silyl trifluoromethanesulfonate mediates a tandem enol silane formation-Mukaiyama aldol reaction in the presence of Hunig’s base. Preformation of the enol silane is unnecessary for efficient reactions, which proceed in 75-97% yield for the addition of aryl methyl ketones and acetate esters to non-enolizable aldehydes. Mechanistic data suggests that free amine is crucial for f...

We report here the synthesis of a novel electroactive polyolefin and demonstrate through a combination of SEC-MALS and DLS how this type of functional polymer can be folded in a controlled fashion from an expanded coil to a tightly wound globule using sequentially activated noncovalent and covalent intra-chain interactions.

Adhesion between the polymer matrix and fillers is an important factor influencing properties of obtained composites. One way to improve interactions at interface modify filler with coupling agents, e.g., silanes. The article presents effect modifying surface mineral a new type silane [triethoxy(ketoimino)silane] on mechanical polyester resin based Composites triethoxy(ketoimino)silane-modified...