an efficient synthesis of polyhydroquinoline derivatives was reported via four-component coupling reactions of aldehydes, 1,3-dicarbonyl ketones (dimedone or 1,3-cyclohexanedione), ethyl acetoacetate or methyl acetoacetate and ammonium acetate in the presence of a catalytic amount of nanocrystalline tio2 under solvent free conditions. the reported method is mild, rapid and has the advantages su...

To investigate the influence of the Morin transition on the photoelectrochemical (PEC) activity of hematite, electronic properties in different magnetic phases were studied on the basis of the first-principles calculations within the GGA+U approximation. The results show that the effective electron mass in the (0001) plane changes remarkably due to the spin−flop transition, while the effective ...

Nanoparticles classified in 4 overall groups containing: Metallic nanoparticles, ceramic nanoparticles, polymeric nanoparticles and semiconductor nanoparticles. These nanoparticles are used in some biomedical applications such as carrying medicine and photographing agents. With attention to different criteria which are both qualitative and quantitative, selecting the most suitable nanoparticles...

A UHV atomic hydrogen-cracking cell has been constructed to produce atomic hydrogen in order to perform in-situ cleaning of semiconductor samples. The cell was calibrated and tested with the objective of cleaning the III-V semiconductor samples such as GaAs. Mass spectroscopy studies during the atomic hydrogen cleaning of the GaAs samples revealed the chemical process of the hydrogen cleaning. ...

Nanoparticles classified in 4 overall groups containing: Metallic nanoparticles, ceramic nanoparticles, polymeric nanoparticles and semiconductor nanoparticles. These nanoparticles are used in some biomedical applications such as carrying medicine and photographing agents. With attention to different criteria which are both qualitative and quantitative, selecting the most suitable nanoparticles...

In this paper we consider electromagnetic field quantization in the presence of a dispersive and absorbing semiconductor quantum dot. By using macroscopic approach and Green's function method, quantization of electromagnetic field is investigated. Interaction of a two-level atom , which is doped in a semiconductor quantum dot, with the quantized field is considered and its spontaneous emission ...

A novel strategy for highly efficient utilization of chiral ammonium salt catalysts has been described in this paper. Three kinds of catalytic functions including iminium catalysis, enamine catalysis, and acid catalysis of chiral ammonium salt catalysts, have been achieved in the enantioselective reduction and alkylation reaction of α,β-unsaturated aldehydes with alcohols.

SUMMARY Today, practical semiconductor products are an integral part of our lives and the infrastructure of society, and this trend will continue in the future. New areas of application will expand into medical, environmental, and agriculture (food)-related fields in addition to the conventional information and communication technology (ICT)-related field. Low-cost semiconductor devices with ad...

The principles that underlie enzyme catalysis also apply to energy coupling processes. A comparison is made between a kinase system that mediates the phosphorylation of glucose by ATP (hexokinase), as the prototype for enzymic catalysis, and the mitochondrial electron-transfer complexes, as the prototypes for energy coupling systems. Induced polarization of chemical bonds and charge separation ...

Regioselective difunctionalization of alkenes has attracted significant attention from synthetic chemists and has the advantage of introducing diverse functional groups into vicinal carbons of common alkene moieties in a single operation. Herein, we report an unprecedented intermolecular atom transfer thiosulfonylation reaction of alkenes by combining gold catalysis and visible-light photoredox...