The preparation of PEGylated fluorescent nanoparticles (NPs) based on atom transfer radical polymerization (ATRP) and “click chemistry” in one-pot synthesis is presented. First, poly(p-chloromethyl styrene-alt-N-propargylmaleimide) (P(CMS-alt-NPM)) copolymer was prepared via reversible addition-fragmentation chain transfer (RAFT) polymerization. Subsequently, the azido-containing fluorene-based...

An alternative method to efficiently synthesize Core-Crosslinked Star polymers (arm-first approach) is described in this work. The star are produced utilizing a two-step, one-pot Sono-RAFT process. N,N′-dimethylacrylamide (DMA) used prepare the arms, whereas N,N′-methylenebis(acrylamide) (MAA) employed as crosslinking agent. reactions were conducted an aqueous medium at room temperature. Using ...

The first detailed study on free-radical polymerization, copolymerization and controlled radical polymerization of the cyclic push-pull-type monomer methylenelactide in comparison to the non-cyclic monomer α-acetoxyacrylate is described. The experimental results revealed that methylenelactide undergoes a self-initiated polymerization. The copolymerization parameters of methylenelactide and styr...

Ionomers containing sodium 4-styrene sulfonate (4SS) and poly(ethylene glycol) methyl ether acrylate (PEGA) were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization. The polymerization was mediated by 1-phenylethyl dithiobenzoate chain transfer agent in a dimethylformamide/water solvent system. Well-defined copolymers of pPEGA-co-4SS were produced with molecula...

For the optimum design of Piled Raft Foundations (PRF), the concept of settlement reducer piles has been applied. However, when these piles are connected to the raft, a high stress may develop in the relatively small number of piles. Therefore, an alternative approach is to disconnect the piles from the raft forming a new system called a non-connected or disconnected piled-raft foundation (NCPR...

A wavelength selective technique for light-induced network formation based on two photo-active moieties, namely ortho-methylbenzaldehyde and tetrazole is introduced. The network forming species are photo-reactive star polymers generated via reversible activation fragmentation chain transfer (RAFT) polymerization, allowing the network to be based on almost any vinylic monomer. Direct laser writi...

A new family of linear polymers with pronounced affinity for arginine- and lysine-rich proteins has been created. To this end, N-isopropylacrylamide (NIPAM) was copolymerized in water with a binding monomer and a hydrophobic comonomer using a living radical polymerization (RAFT). The resulting copolymers were water-soluble and displayed narrow polydispersities. They formed tight complexes with ...

A technique for the continuous on-line monitoring of polymerization processes by electrospray ionization mass spectrometry (ESI-MS) is presented via coupling with a commercial microreactor system. The potential is demonstrated by monitoring polymerizations in real time under synthesis conditions. Furthermore, a single acrylate monomer insertion into a oligo-RAFT agent, as used in the synthesis ...

• Controlled radical polymerization. Low-energy miniemulsion. Nanoparticle shape, size, and charge. Size, charge are key parameters of nanoparticles, variations in these can significantly impact their properties applications. Among various nanoparticle synthesis methods, the combination low-energy miniemulsions with reversible addition-fragmentation chain-transfer (RAFT) polymerization allows f...