Sub-micrometer-sized CdS spheres were synthesized by hydrothermal and solvothermal reactions using Cd(NO3)2.4H2O and CH4N2S raw materials at a constant stoichiometric 1 : 2, Cd : S molar ratio. Various conditions such as solvent type (water and/or ethanol), reaction time and temperature were examined for the synthesis of the targets. The sy...

Two new multi-component molecular complexes of cytosine and 5-fluorocytosine with 4-chloro-3,5-dinitrobenzoic acid are presented. Materials synthesis was achieved initially by evaporative crystallisation and the crystal structures determined. The process was then successfully transferred into a controlled small scale cooling crystallisation environment, with bulk samples shown to be representat...

A multi-dimensional extra-large pore silicogermanate zeolite, named ITQ-54, has been synthesised by in situ decomposition of the N,N-dicyclohexylisoindolinium cation into the N-cyclohexylisoindolinium cation. Its structure was solved by 3D rotation electron diffraction (RED) from crystals of ca. 1 μm in size. The structure of ITQ-54 contains straight intersecting 20 × 14 × 12-ring channels alon...

Thermolysis of the single source precursor (Et2Bi)2Te in DIPB at 80 °C yielded phase-pure Bi4Te3 nanoparticles, while mixtures of Bi4Te3 and elemental Bi were formed at higher temperatures. In contrast, cubic Bi2Te particles were obtained by thermal decomposition of Et2BiTeEt in DIPB. Moreover, a dual source approach (hot injection method) using the reaction of Te(SiEt3)2 and Bi(NMe2)3 was appl...

A size-controlled synthesis of gold nanoparticles has been developed by the thermolysis of AuCl(SMe2) in the presence of alkylamines at 120 ◦C. In the procedure, the key intermediate was [Au(NH2R)2]Cl, detected by electrospray ionization (ESI) mass spectrometry. This thermally unstable intermediate was reduced by alkylamines under mild conditions to produce alkylamine-capped gold nanoparticles....

Supramolecular hydrogels are composed of self-assembled solid networks that restrict the flow of water. l-Phenylalanine is the smallest molecule reported to date to form gel networks in water, and it is of particular interest due to its crystalline gel state. Single and multi-component hydrogels of l-phenylalanine are used herein as model materials to develop an NMR-based analytical approach to...

Differential scanning calorimetry (DSC) and X-ray powder diffraction (PXRD) have been used to determine the phase behavior of the binary mixtures of undecanoic acid (A) and undecylamine (B) in the bulk. In addition, we report DSC data that indicates very similar behavior for the solid monolayers of these materials adsorbed on the surface of graphite. The two species are found to form a series o...

The evolution of size and size distribution during hydrothermal synthesis of nanocrystalline CoFe2O4 has been studied by in situ synchrotron powder X-ray diffraction (PXRD). Varying synthesis temperature or [OH(-)] concentration in the precursor proves to have no significant effect on the final volume-weighted nanocrystallite sizes (∼12 nm) of CoFe2O4. However, analysis by whole powder pattern ...

From centuries human has been afflicted by urinary calculi (Urolithiasis). These calculi are formed from crystal aggregation and retention in the urinary tract. The incidence and prevalence of urolithiasis may be related to various factors including age, sex, ethnicity, diet, fluid intake, genetic predisposition, climatic conditions, and urinary tract infections. Study of chemical composition a...

Abstract Among all iron oxides, hematite (α-Fe 2 O 3 ), goethite (α-FeOOH), and ferrihydrite (FeOOH⋅ n H O) are the most common mineral species. While immobilization of Mo 6+ by surface adsorption on ferric oxides has been studied extensively, mechanisms incorporation in their structure have researched little. The objective this study was to investigate relation between content its structural h...