Hairpin polyamide-chlorambucil conjugates containing an alpha-diaminobutyric acid (alpha-DABA) turn moiety are compared to their constitutional isomers containing the well-characterized gamma-DABA turn. Although the DNA-binding properties of unconjugated polyamides are similar, the alpha-DABA conjugates display increased alkylation specificity and decreased rate of reaction. Treatment of a huma...

the main objective of the present work was to synthesis polyamide 6 through anionic polymerization of ε-caprolactam in an internal mixer. the reaction time and the rheological properties of samples during the polymerization were studied. the samples were characterized by thermo gravimetry analysis (tga), differential scanning calorimeter (dsc) and ft-ir spectrometer. the melt flow behavior and ...

Recent findings regarding nanofiltration (NF) have led to indications that it can be successfully used for separation of various biological solutions. As a novelty, this paper is the first investigate impact feed pretreatment process on NF membrane performance 1,3-propanediol (1,3-PD) fermentation broths. For purpose, prior process, was purified by microfiltration (MF) and ultrafiltration (UF) ...

practical applications of conducting polymers such as polyaniline as membranes are particulary limitedbecause of their poor mechanical properties. however by mixing polyaniline with some conventional insulatingpolymers such as nylon and preparation composite films through solvent casting or blending, it seems to be asuitable way in order to increase the mechanical properties of the conducting p...

The interest in recycled carbon fiber (rCF) is growing rapidly and the supply chain for these materials gradually being established. However, processing routes, material intermediates properties of rCF composites are less understood designers to adopt them into practice. This paper provides a practical pathway rCFs conjunction with low cost and, most part, commodity thermoplastic resins, namely...