α-amino nitriles are synthesized in a one-pot, three-component coupling of aldehydes (or ketones), aniline, and trimethylsilyl cyanide using a catalytic amount of choline chloride.2zncl2 as a bio lewis acidic ionic liquid. mild lewis acidic characteristic of this ionic liquid allows efficient synthesis of α-amino nitriles from acid sensitive aldehydes.

For more than three decades, Oxidative Coupling of Methane (OCM) process has been comprehensively investigated as an attractive alternative for the commercially available ethylene production technologies such as ethane and naphtha cracking. Developing a suitable catalyst and proper reactor feeding policy, reviewing and deploying the efficient methods in the separation and purification of the un...

for more than three decades, oxidative coupling of methane (ocm) process has been comprehensively investigated as an attractive alternative for the commercially available ethylene production technologies such as ethane and naphtha cracking. developing a suitable catalyst and proper reactor feeding policy, reviewing and deploying the efficient methods in the separation and purification of the un...

oxidative coupling of methane has been studied over (mn+a+w)/sio2 catalysts in a continuous–flow microreactor, where a represents an alkali ion of li, na, k or cs having different weight percents. the main aim of this study is to find the role of alkali ions in interaction between mn and w species with sio2 to make a proper structure for catalyzing oxidative coupling of methane (ocm) reaction. ...

in this article, the effect of operating conditions, such as temperature, gas hourly space velocity (ghsv), ch4/o2 ratio and diluents gas (mol% n2) on ethylene production by oxidative coupling of methane (ocm) in a fixed bed reactor at atmospheric pressure was studied over mn/na2wo4/sio2 catalyst. based on the properties of neural networks, an artificial neural network was used for model develo...

ground state geometries have been computed using density functional theory (dft) at b3lyp/6-31g(d,p) level of theory. the excitation energies and spectroscopic parameters have been computed using long range corrected (lc) hybrid functional by time dependent density functional theory (tddft) with lc-blyp level of theory. the polarizable continuum model (pcm) has been used for evaluating bulk sol...

Measurement of the triple Higgs boson coupling is one of the most important goals of the Higgs physics at a future ee linear collider (LC) experiment. This would provide the first direct information on the Higgs potential that is responsible for electroweak symmetry breaking. The existence of the triple Higgs coupling is a characteristic feature of the spontaneous breaking of the electroweak sy...

We study the synchronization of two chaotic maps with unidirectional (master-slave) coupling. Both maps have an intrinsic delay n1, and coupling acts with a delay n2. Depending on the sign of the difference n1 − n2, the slave map can synchronize to a future or a past state of the master system. The stability properties of the synchronized state are studied analytically, and we find that they ar...

Phase transitions in open quantum systems, which are associated with the formation of collective states of a large width and of trapped states with rather small widths, are related to exceptional points of the Hamiltonian. Exceptional points are the singularities of the spectrum and eigenfunctions, when they are considered as functions of a coupling parameter. In the present paper this paramete...

in this paper a novel design of all-optical half-subtractor based on nonlinear directional coupler is proposed. by using four waveguides and appropriately adjusting the refractive indices and selecting the proper length of waveguides, halfsubtractor function can be obtained. the operation of this function is simulated by rsoft cad-layout (beamprop) simulator. the simulation results confirm the ...