Ionic liquids such as 1,3-dialkylimidazolium salts make excellent catalysts and solvents for synthesis of dialkyl 2-(dialkoxyphosphoryl)-3-(1-oxo-1-H-phthalazin-2-yl)succinates from 2H-phthalazin-1-one, dialkyl acetylenedicarboxylates, and trialkyl phosphites. Under similar conditions, triphenyl phosphite led to dialkyl 2-(diphenoxyphosphoryl)-3-(1-oxo-1-H-phthalazin-2-yl)succinates. The ionic ...

The title compound, poly[zinc(II)-mu-butane-1,4-diamine-mu-(hydrogen phosphito)] (C(4)H(12)N(2))(0.5)[ZnHPO(3)], is a hybrid organic-inorganic solid built up from 1,4-diaminobutane molecules, Zn(2+) cations (coordinated by three O atoms and one N atom) and HPO(3)(2-) hydrogen phosphite groups. The organic species bonds to the Zn atom as an unprotonated ligand, resulting in it acting as a bridge...

The direct UV irradiation of cyclic phosphites 1–4 was carried out in argon-saturated solvents. In all cases examined, the rearranged, ring-contracted Photo-Arbuzov phosphonate was the major product formed with isolated yields ranging from 40 to 50%. These phosphonate photoproducts, 5–8, represent novel, bicyclic, aromatic phosphonate systems never before described in the literature of heterocy...

In the title compound, C(4)H(8)N(3)O(4)P(+)·H(2)PO(3) (-), the cytosine mol-ecule is monoprotonated and the phospho-ric acid is in the monoionized state. Strong hydrogen bonds, dominated by N-H⋯O inter-actions, are responsible for cohesion between the organic and inorganic layers and maintain the stability of this structure.

Allenamides participate as two-carbon components in an intermolecular [2 + 2 + 2] cycloaddition with alkenes and aldehydes when treated with catalytic amounts of a phosphite gold complex. The reaction is highly regio- and chemoselective, and works with different types of alkenes, including styrenes, enol ethers or enamides, as well as with aromatic and aliphatic aldehydes. Accordingly, differen...

A bacterial flavin-containing monooxygenase (FMO), fused to phosphite dehydrogenase, has been used to explore its biocatalytic potential. The bifunctional biocatalyst could be expressed in high amounts in Escherichia coli and was able to oxidize indole and indole derivatives into a variety of indigo compounds. The monooxygenase also performs the sulfoxidation of a wide range of prochiral sulfid...

the aim of this work is to probe the influence of nanoclay and turmeric spends content on microcrystalline of vinyl ester hybrid nanocomposites. a series of vinyl ester hybrid nanocomposites have been fabricated with varying amounts of ts viz., 0, 2.5, 5, 7.5 and 10 % w/w along with 2% nanoclay. the microcrystalline parameters such as crystallite size and lattice strain of vinyl ester hybrid na...