Based on a microscopic density functional theory we calculate the internal structure of the three-phase contact line between liquid, vapor, and a confining wall as well as the morphology of liquid wetting films on a substrate exhibiting a chemical step. We present a refined numerical analysis of the non-local density functional which describes the interface morphologies and the corresponding li...

Evidence for internal and external interface transitions in ceramics and metals is copious. The work described here lays out a framework for predicting interface transitions and including them on bulk phase diagrams. Advances in understanding possible grain boundary transitions in singleand binary-component materials have been made with energetics modelled with the phase-field model due to Koba...

To clarify conflicting reports on the composition and stability of H2O and D2O adsorbates on Ru(0001), we have conducted correlated experiments in two laboratories using X-ray photoelectron spectroscopy and thermal desorption spectroscopy, without and after controlled electron irradiation. Both species form molecular wetting layers; D2O stays molecular to desorption while H2O undergoes a therma...

We have used molecular dynamics simulations to construct a microcanonical caloric curve for a 1415 atom Ni icosahedron. Prior to melting, the Ni cluster exhibits static solid-liquid phase coexistence. Initially, a partial icosahedral structure coexists with a partially wetting melt. However, at energies very close to the melting point the icosahedral structure is replaced by a truncated decahed...

For partial wetting, motion of the triple liquid-gas-solid contact line is influenced by heterogeneities of the solid surface. This influence can be strong in the case of inertial (e.g. oscillation) flows where the line can be pinned or move intermittently. A model that takes into account both surface defects and fluid inertia is proposed. The viscous dissipation in the bulk of the fluid is ass...

Surface acoustic waves are used to actuate and process smallest amounts of fluids on the planar surface of a piezoelectric chip. Chemical modification of the chip surface is employed to create virtual wells and tubes to confine the liquids. Lithographically modulated wetting properties of the surface define a fluidic network, in analogy to the wiring of an electronic circuit. Acoustic radiation...

Surface acoustic waves are used to actuate and process smallest amounts of fluids on the planar surface of a piezoelectric chip. Chemical modification of the chip surface is employed to create virtual wells and tubes to confine the liquids. Lithographically modulated wetting properties of the surface define a fluidic network, in analogy to the wiring of an electronic circuit. Acoustic radiation...

We study microreactors with internal fields of posts as typical examples of structured microreactors to elucidate flow fields and their implications for mass transfer. Laser-induced fluorescence (LIF) visualization combined with image analysis is used to systematically quantify key features such as interfacial area, phase holdup and the characteristics of the post-wetting layer. The subsequent ...