The reactions of [(thf)2TiCl4] with sodiated 2,2’-bis[2-hydroxy-3,5-di(tert-butyl)benzylideneamino]-1,1’-biphenyl (1 a) and 2,2’-bis[2-hydroxy-3,5-di(tert-butyl)benzylideneamino]-4,4’-dimethyl-1,1’-biphenyl b) yield the corresponding Ti complexes 2 a b. Similarly, 1 reacts [(thf)2ZrCl4] to Zr derivative 3. For a, mixture cis-β trans isomers were observed in solution whereas congener exclusively...

The combination of in situ pair distribution function (PDF) analysis and small-angle X-ray scattering (SAXS) enables the formation mechanism metal oxido nanoclusters cluster–solvent interactions as they take place. Herein, we demonstrate method for clusters with a [Bi38O45] core. Upon dissolution crystalline [Bi6O5(OH)3(NO3)5]?3 H2O DMSO, an intermediate rapidly forms, which slowly grows to sta...

In recent years, glucose oxidase (GOx) has aroused great research interest in the treatment of diseases related to abnormal metabolisms like cancer and diabetes. However, as a kind endogenous oxido-reductase, GOx suffers from poor stability system toxicity vivo. order overcome this bottleneck, is encapsulated calcium-based biomaterials (CaXs) such calcium phosphate (CaP) carbonate (CaCO3) by us...