In the title compound, [CaCs2(C2O4)2(H2O)4] n , the Ca(2+) ion, lying on a twofold rotation axis, is coordinated by four O atoms from two oxalate ligands and two bridging water mol-ecules in an octa-hedral geometry. The Cs(+) ion is coordinated by seven O atoms from six oxalate ligands, one bridging water and one terminal water mol-ecule. The oxalate ligand displays a scarce high denticity. The...

the a f f i x e s i n a l a n g u a g u e are a masive w e b o f morfolexical elements formed b y t w o bases ; t h e root and t h e bound . t h e combination o f these t w o link the meaning o f a w o rd with a concept . t h e a i m o f t h e present paper i s t o study t h e similitud and dissimilitude i n t h e funtion o f these suffixes i n b o t h spanish a n d persian languages . we will ...

The title complex, [Pr(2)(C(4)H(2)O(4))(3)(C(4)H(4)O(4))(H(2)O)(2)](n), was synthesized by reaction of praseodymium(III) nitrate hexa-hydrate with fumaric acid in a water-ethanol (4:1) solution. The asymmetric unit comprises a Pr(3+) cation, one and a half fumarate dianions (L(2-)), one half-mol-ecule of fumaric acid (H(2)L) and one coordinated water mol-ecule. The carboxyl-ate groups of the fu...

the genus onobrychis is an important forage crop consisting of approximately 130 annual and perennial species. in this study, 13 populations of five onobrychis species were analyzed. the basic chromosome number varied from x=7 to x=8. according to stebbins’ classification, populations such as o. aucheri subsp. psammophila, o. crista-galli (1) and o. crista-galli (2) were classified in symmetric...

Olive-mill wastewater (OMW), an effluent of olive oil extraction process, is annually produced in huge amounts in olive growing areas. An interesting option for its disposal is the spreading on agricultural land, provided that phytotoxic effects are neutralized. The objective of the present investigation was to evaluate the potential of an enzyme-based treatment in removing OMW phytotoxicity. T...

The inhibition of the type-3 copper enzyme tyrosinase by halide ions was studied by kinetic and paramagnetic (1)H NMR methods. All halides are inhibitors in the conversion of l-3,4-dihydroxyphenylalanine (l-DOPA) with apparent inhibition constants that follow the order I(-) < F(-) << Cl(-) < Br(-) at pH 6.80. The results show that the inhibition arises from the interaction of halide with both t...

The dinuclear copper enzyme tyrosinase (Ty) from genetically engineered Streptomyces antibioticus has been investigated in its paramagnetic half-met form [Cu(I)-Cu(II)]. The cw EPR, pulsed EPR, and hyperfine sublevel correlation spectroscopy (HYSCORE) experiments on the half-met-Ty and on its complexes with three different types of competitive inhibitor are reported. The first type includes p-n...