We have analyzed structure, stability, and Ru-NO bonding of the trans-[RuCl(NO)(NH3)4]2+ complex by using relativistic density functional theory. First, we focus on the bond dissociation energies associated with the three canonical dissociation modes leading to [RuCl(NH3)4]++NO+, [RuCl(NH3)4]2++NO, and [RuCl(NH3)4]3++NO-. The main objective is to understand the Ru-NO+ bonding mechanism in the c...

This paper introduces methods to coordinate black box simulations in the construction of metamodels for situations in which we have to deal with coupled black boxes. We define three coordination methods: parallel simulation, sequential simulation and sequential modeling. To compare these three methods we focus on five aspects: throughput time, flexibility, simulated product designs, coordinatio...

BACKGROUND AND PURPOSE Conventional therapies fail to restore normal gait to many patients after stroke. The study purpose was to test response to coordination exercise, overground gait training, and weight-supported treadmill training, both with and without functional neuromuscular stimulation (FNS) using intramuscular (IM) electrodes (FNS-IM). METHODS In a randomized controlled trial, 32 su...

ENWEndNote BIBJabRef, Mendeley RISPapers, Reference Manager, RefWorks, Zotero AMA Şahin S, Serap Ünalan PC. Job satisfaction of family physicians in European countries with different strengths care coordination. Family Medicine & Primary Care Review. 2022;24(4):341-347. doi:10.5114/fmpcr.2022.120859. APA Şahin, S., Serap, Ünalan, P. C. (2022). Review, 24(4), 341-347. https://doi.org/10.5114/fmp...

Coordination in collective wage setting can constrain potential monopoly gains to unions non-traded-goods industries. Countries with national coordination thus stabilize overall employment against fluctuations and shocks the world economy. We investigate this argument by exploring within-country variation exposure competition from China 13 European countries. Our estimates demonstrate that coun...

this  article  provides  an  overview  on  preparation,  design,  crystal structure  and  properties  of  some  metal-organic  frameworks  of carboxylate coordination polymers mixed with pyridine-functionality linkers  prepared  in  our  laboratory.  the  article  covers  coordination polymers  in  two-  and  three-dimensional  supramolecular architectures. the reported coordination polymers ex...

BACKGROUND Japan has introduced an acute psychiatric care unit to the public healthcare insurance program, but its requirement of a shorter length of stay could lead to discharges without proper discharge planning. The aim of this study was to examine the association between the implementation of discharge planning and the length of stay of acute psychiatric inpatients in Japan. METHODS This ...