The title compound, [Tb(NO(3))(3)(C(12)H(16)N(3)O(2))(2)], was prepared from the nitroxide radical ligand 4,4,5,5-tetra-methyl--2-(pyridin-2-yl)-imidazoline-1-oxyl-3-oxide and Tb(III) nitrate. The Tb(III) ion adopts a doubly-capped square-anti-prismatic coord-ination environment defined by three chelating nitrate anions and two N,O-bidentate nitronyl nitroxide radical ligands. Weak C-H⋯O hydrog...

In the title compound, {[Cu(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Cu(II) ion lies on an inversion center and is six-coordinated in an octa-hedral environment by four N atoms from four different 1,1'-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol-ecules. Bridging by the ligands results in a ribbon structure. Adjacent ribbons are linked to the nitrate anions ...

The results from this study illustrate the first time electrospray ionization-ion mobility spectrometry (ESI-IMS) has been used to separate inorganic cations in aqueous solutions. Using ESI-IMS nine inorganic cation solutions were analyzed. Counter ions affected both the sensitivity and the identity of the response ions. Aluminum sulfate, lanthanum chloride, strontium chloride, uranyl acetate, ...

Ionic liquids (ILs) are expected to have specific properties as solvents for chemical reactions in view of solution chemistry. Among physicochemical properties, liquid structure, acid–base, and electron-pair donating and accepting abilities of solvent play a crucial role in ion-solvation and acid–base, metal-ion complexation, and electrochemical reactions. Various types of ILs have been develop...

Control of size and shape is a challenge in nanoparticle synthesis. Synthetic and biosynthetic (both extracellular and intracellular) methods are used to prepare silver nanoparticle (SNP). In this study, the behavior of three strains of Staphylococcus aureus (S. aureus) was investigated in the presence of silver nitrate intra- and extracellularly. S. aureus strains biosynthesized SNPs intracell...

Control of size and shape is a challenge in nanoparticle synthesis. Synthetic and biosynthetic (both extracellular and intracellular) methods are used to prepare silver nanoparticle (SNP). In this study, the behavior of three strains of Staphylococcus aureus (S. aureus) was investigated in the presence of silver nitrate intra- and extracellularly. S. aureus strains biosynthesized SNPs intracell...

In the mononuclear title compound, [Ag(NO3)(C6H6N2O)2], the Ag(I) atom is located on a twofold rotation axis and the nitrate-chelated Ag(I) atom is further coordinated by two aromatic N atoms of hydroxyl-amine ligands in a distorted tetra-hedral geometry. In the crystal, the nitrate ion has 2 symmetry with the N atom and one O atom located on the twofold rotation axis, and is linked to hy-droxy...

In the title compound, [Cu(NO(3))(2)(C(15)H(19)N(3)O)], the Cu(II) ion is coordinated by the N atoms of the tetra-dentate 3-[bis-(2-pyridyl-meth-yl)amino]-propanol ligand and two O atoms from two monodentate nitrate anions, resulting in a distorted square-pyramidal environment. An inter-molecular O-H⋯O hydrogen-bonding inter-action between the free hy-droxy group of the ligand and a nitrate O a...

Establishment of great industrial centers and ports along the Khur-Musa Estuary in Mahshahr Port (Khuzestan, Iran) have been discharged a high volume of industrial and non-industrial pollutants to this estuary. The most important pollutants in Khur-Musa include industrial wastes and effluents including ammonia and urea units. This research aimed to survey the qualitative parameters of effluent ...

In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the Co(II) ion is located on an inversion center and is six-coordinated in an octa-hedral environment defined by four N atoms of the pyridine rings and two O atoms of the nitrate anions. The ligands link the Co(II) ions into a linear chain running along [201]. One O atom of the nitrate ligand is disordered over two positions with ...