The use of chiral Ni(II)-salen derivatives was examined in mediated electrohydrocyclization (EHC) reactions. Cyclic voltammetry established the existence of a catalytic current. Bulk electrolysis revealed a slight change in the diastereoselectivity of the cyclizations. Density functional theory (DFT) computational studies showed that Ni(II)-salen and Zn(II)-salen were the best metal-salens for ...

We have prepared supramolecular systems of chiral Schiff base Ni(II), Cu(II), Zn(II) complexes and colloidal gold nanoparticles (AuNP) of 10 nm diameters. They demonstrated that direct adsorption of chiral Schiff base metal complex on the surface of AuNP owing to observation of clear induced CD spectra for the first time. We observed and discussed induced CD bands on AuNP from chiral Schiff bas...

We have here synthesized new chiral Schiff base Ni(II), Cu(II), Zn(II) complexes (Ni, Cu, Zn) and hybrid materials with azobenzene (AZ) in polymethyl methacrylate (PMMA). Linearly polarized UV light irradiation of these hybrid materials slightly increased their optical anisotropy of AZ as well as the complexes, which were measured with polarized IR and UV-Vis spectra and discussed based on TD-D...

The present study was undertaken for assessing the level of heavy metals such as copper, nickel and zinc in water, water hyacinth and soil samples of Rupahi beel, Nagaon, Assam. Metals were detected using flame atomic absorption spectrophotometry. The results revealed that by and large all the three metals are present in all the samples. The average concentration of Cu, Ni and Zn in both water ...

Some novel transition metal [Co(II), Cu(II), Ni(II) and Zn(II)] complexes of substituted pyridine Schiff-bases have been prepared and characterized by physical, spectral and analytical data. The synthesized Schiff-bases act as deprotonated tridentate for the complexation reaction with Co(II), Ni(II) and Zn(II) ions. The new compounds, possessing the general formula [M(L)(2)] where [M=Co(II), Cu...

The objectives of this study were to investigate the seasonal and spatial variations of heavy metal pollution in the overlying water and surface sediments of the Tiaozi River, a tributary of the Liao River, which is one of the seven major rivers and one of the most heavily-polluted rivers in China. Water and sediment samples were collected over four seasons, analyzed for heavy metals (Pb, Cu, N...

the  present study was aimed  at comparing the ability of three crop plants for phytoremediation of zinc (zn) and nickel (zn) from soils. a factorial (3×2×3) experiment based on rcbd was  used to compare the treatments,  and was repeated three times. the first factor was crop type (wheat, clover and rapeseed), the second factor was heavy metal types (zinc (zn) and nickel (ni)) and the third fac...

The Ni hyperaccumulator Strepthanthus polygaloides (Brassicaceae) is one of a handful of Ni hyperaccumulators known from continental North America. Surveys have revealed four distinctive morphs of this species, relying primarily on floral traits (sepal color and shape): a purple sepal morph (P), a yellow sepal morph (Y), a morph in which sepals start yellow and mature to purple (Y/P), and a mor...

Cellulose-based Ni/Cr (Ni/Cr-C) and cellulose-based Zn/Cr (Zn/Cr-C) composite materials have been successfully carried out, which is indicated by the XRD, FTIR, BET analysis. Layered double hydroxide (Ni/Cr-LDH) increased surface area from 0.128 m2/g to 2.207 in Ni/Cr-C composites, layered (Zn/Cr-LDH) also 0.133 3.714 Zn/Cr-C composites. The pHpzc of material this study pH 5.94-8.43, while opti...