Single-layered molybdenum disulphide with a direct bandgap is a promising two-dimensional material that goes beyond graphene for the next generation of nanoelectronics. Here, we report the controlled vapour phase synthesis of molybdenum disulphide atomic layers and elucidate a fundamental mechanism for the nucleation, growth, and grain boundary formation in its crystalline monolayers. Furthermo...

Molybdenum toxicity is a controversial subject. However, much of the contention is due to inappropriate diagnosis. This paper shows the flaw in using plasma copper levels alone to diagnose a molybdenum toxic condition, based on samples from >7,500 dairy cattle. Evidence that thiomolybdates are absorbed into the ruminant body and have toxic effects (molybdenum toxicity) on critical copper metall...

In this work, polyimide (PI) was coated onto an ultrafine gilt molybdenum wire in order to protect the gilt surface and prepare an electrically stable wire mesh material which can be widely used in space. The surface of the PI-coated gilt molybdenum wires was characterized using FTIR, SEM, and EDS. Factors such as temperature stability of the PI coating, mechanical properties of the PI-coated g...

Molybdenum disulphide is a layered transition metal dichalcogenide that has recently raised considerable interest due to its unique semiconducting and opto-electronic properties. Although several theoretical studies have suggested an electronic phase transition in molybdenum disulphide, there has been a lack of experimental evidence. Here we report comprehensive studies on the pressure-dependen...

Molybdenum(VI) oxide reacts with molten LiC1-KCI eutectie at 450 ~ to form MOO2C12, which probably is present as an anion MoO2Cl4 =, and pyromolybdate, Mo207 =. Both of these species are electrochemically reduced to MOO2, which can be reoxidized to MoO2CI2 by current reversal. A second reduction step, observed whether MoO3 or Mo2072is added to the melt, can be attributed to the reduction of MoO...

Activity of nitrate reductase from Triticum aestivum L. seedlings was decreased by deficiencies of molybdenum, zinc, and chlorine. Nitrate accumulated in molybdenum-deficient seedlings, declined in zinc-deficient seedlings, and was unaffected by the other micronutrient treatments. Glutamic acid dehydrogenase activity was decreased by deficiency of molybdenum, the only nutrient that affected the...

Interface confined reactions, which can modulate the bonding of reactants with catalytic centres and influence the rate of the mass transport from bulk solution, have emerged as a viable strategy for achieving highly stable and selective catalysis. Here we demonstrate that 1T'-enriched lithiated molybdenum disulfide is a highly powerful reducing agent, which can be exploited for the in-situ red...

Ferron has been used as an analytical reagent for the extractive spectrophotometric determination of molybdenum(V) obtained from the reduction of molybdenum(VI) with ascorbic acid. Molybdenum(V) in presence of a large number of cations, anions and complexing agents forms a yellow complex with ferron that is quantitatively extractable into tri-n-octylamine-chloroform from 1 M H2SO4 medium. The c...

The present research paper deals with the oxidation process of molybdenum ore. The main target of the present study is the up-gradation of MoO3 from roasted molybdenum ore by a leaching process without waste generation. The most important application of hydrometallurgical processing is the leaching process of the ore and it is the primary process to make pure metal from ore. The present investi...

Hydrogen production through water splitting has been considered as a green, pure and high-efficient technique. As an important half-reaction involved, hydrogen evolution reaction is a complex electrochemical process involving liquid-solid-gas three-phase interface behaviour. Therefore, new concepts and strategies of material design are needed to smooth each pivotal step. Here we report a multis...