Efficient, low-cost, and stable electrocatalysts for water splitting are highly desirable. Herein, three-dimensional (3D) Ni2P nanosheet arrays were fabricated simultaneously modulated by heterostructure engineering Mn doping (Mn-doped Ni2O3/Ni2P Mn-doped NixSy/Ni2P) via a facile hydrothermal reaction subsequent phosphorization sulfurization. Due to the doping, synergistic effect in heterostruc...