The new ligands, 1-(4-isopropyl phenyl)-4-(2-pyridyl)-1,2,3-triazole, 1 and 1-(mesityl)-4-(2-pyridyl)-1,2,3-triazole, 2 were prepared by the reactions of the respective azides with 2-ethynylpyridine following the "click method". These ligands together with the reported ligands 1-(phenyl)-4-(2-pyridyl)-1,2,3-triazole, 3 and 1-(benzyl)-4-(2-pyridyl)-1,2,3-triazole, 4 were reacted with palladium a...

PURPOSE Resin to metal bond strength of two commercial and one experimental metal-resin bonding system for crown and bridge veneer composites was evaluated. MATERIALS AND METHODS All specimens were prepared and tested according to ISO 10477 Amendment 1. A high precious alloy (HPA), a Co/Cr-alloy (Co/Cr) and pure titanium (Ti) were wet-ground to a final surface finish of 800 grit and air-dried...

Received: 20 February 2016 Accepted: 19 March 2016 Published online: 30 June 2016 Printed: 30 June 2016 Direct and selective carbon‐hydrogen bond functionalization has attracted enormous attention because it provides more efficient strategies for preparing valuable functional molecules from easily available substrates. Significant and exciting developments in functionalization of un‐activation ...

Fragmentation behavior of two classes of cyclodepsipeptides, isariins and isaridins, obtained from the fungus Isaria, was investigated in the presence of different metal ions using multistage tandem mass spectrometry (MS(n)) with collision induced dissociation (CID) and validated by NMR spectroscopy. During MS(n) process, both protonated and metal-cationized isariins generated product ions belo...

Lightweight ceramic-metal combinations are one option for advanced vehicle and other structural applications. These structures can require the fabrication of large area arrays of ceramic tiles on a metallic backing. However, the process of fabricating a combination of lightweight ceramics and metals is complicated by the need to bond these very dissimilar materials together. For severe applicat...

Introduction: Failures might occur at metal‒porcelain interfaces as a problem with metal‒ceramic restorations even with the application of airborne-particle abrasion technique. This study was undertaken to evaluate the effect of Nd:YAG laser treatment on the bond strength of porcelain fused to metal. Methods:  Twenty-four cylindrical specimens (4 mm in diameter and 4 mm in height) were made of ...

Abstract Background and Aim: High chipping rates of the veneering porcelain of zirconia ceramic restorations have been reported in clinical studies. Thus, the shear bond strength (SBS) between the zirconia core and veneering porcelain requires investigation. Materials and Methods: In this in-vitro study, at first, using a computer-aided design/computer-aided manufacturing (CAD/CAM) machine, 1...

In the monomeric title titanium(III) compound, [Ti(C(12)H(21)N(2)Si)(2)Cl], the metal atom is surrounded by two N-silylated anilide ligands in an N,N''-chelating mode. The two ends of the N-Si-N chelating unit exhibit different affinity to the metal center. The Ti-N(amine) bond is longer than the Ti-N(anilide) bond by about 0.29 Å. The two ligands are arranged trans to each other and the mol-ec...

The aim of this study was to evaluate the shear bond strength of Co-Cr and Ni-Cr metal alloys and a specific ceramic, submitted to different thermocycling immersion times. Sixty metal-ceramic specimens were confectioned and standardized in cylindricalformat. Three thermocycling conditions were evaluated: without thermocycling, 3,000 cycles (5 degrees C/55 degrees C+/-1) with 30s of immersion ti...

Heterobimetallic complexes containing short uranium-group 10 metal bonds have been prepared from monometallic IU(IV)(OAr(P)-κ(2)O,P)3 (2) {[Ar(P)O](-) = 2-tert-butyl-4-methyl-6-(diphenylphosphino)phenolate}. The U-M bond in IU(IV)(μ-OAr(P)-1κ(1)O,2κ(1)P)3M(0), M = Ni (3-Ni), Pd (3-Pd), and Pt (3-Pt), has been investigated by experimental and DFT computational methods. Comparisons of 3-Ni with t...