The title compound, penta-iron tripraseodymium dodeca-oxide (PrIG), has an iron garnet structure. There are two Fe site symmetries. One of the Fe atoms is coordinated by six O atoms, forming a slightly distorted octa-hedron, and has site symmetry. The other Fe atom is coordinated by four O atoms, forming a slightly distorted tetra-hedron, and has site symmetry. FeO(6) octa-hedra and FeO(4) tetr...
