The aggregation phenomena in aqueous solutions of hydrophobically modified (HM) chitosan, containing 4 mol % of n-dodecyl side chains, were studied by viscometry and fluorescence spectroscopy with pyrene as a probe. The results are compared with those for unmodified chitosan. Surprisingly, fluorescence data reveal the appearance of intermolecular hydrophobic aggregates both in chitosan and in H...

Reynolds-averaged Navier–Stokes (RANS) methods often cannot predict shock/turbulence interaction correctly. This may be because RANS models do not account for the unsteady motion of the shock wave that is inherent in these interactions. Previous work proposed a shock-unsteadiness correction that significantly improves prediction of turbulent kinetic energy amplification across a normal shock in...

Reynolds averaged Navier-Stokes methods often cannot predict shock/turbulence interaction correctly. This may be because RANS models do not account for the unsteady motion of the shock wave that is inherent in these interactions. Sinha et al. [Phys. Fluids, Vol. 15, No. 8 (2003)] propose a shock-unsteadiness correction that significantly improves turbulence prediction across a normal shock in a...

The structural and dynamical properties of water are known to be affected by ion solvation. However, a consistent molecular picture that describes how and to what extent ions perturb the water structure is still missing. Here we apply 2D Raman-terahertz spectroscopy to investigate the impact of monatomic cations on the relaxation dynamics of the hydrogen-bond network in aqueous salt solutions. ...

Mucus was collected daily from open-ended pouches established surgically in three mini-pigs. After a five day control period bromhexine hydrochloride (BHCl) was administered to each pig at dose levels of 0.5, 1.0 and 2.0 mg.kg-1 twice daily for five days. Each study period was followed by a five day washout period, when mucus was collected but no drug given. The viscoelastic properties of each ...