a new schiff base ligand, 2,2'-{pyridine-2,6-diylbis[nitrilo(e)methylylidene]}bis(4 bromophenol),has been synthesized by reaction of the 2,6-diamino pyridine with 5-bromo salicylaldehyde at ethanolunder refluxing. the structure of the synthesized compound resulted from the ir, 1hnmr, ms anduv spectroscopy and elemental analysis data. formation constant (kf) value of it’s complexes withcu2+, ni2...

 A series of seven new complexes of zirconium and hafnium with bulky ω-aryloxyalkyl substituted indenyl ligands were synthesized and characterized by NMR spectroscopy and elemental analysis. These complexes were activated with methylaluminoxane and tested for homogeneous ethylene polymerization. The zirconium catalysts showed higher activities than their hafnium an...

Let $X$ be a sufficiently nice scheme. We survey some recent progress on dualizing complexes. It turns out that a complex in $kinj X$ is dualizing if and only if tensor product with it induces an equivalence of categories from Murfet's new category $kmpr X$ to the category $kinj X$. In these terms, it becomes interesting to wonder how to glue such equivalences.

2-[3-(2-formylnaphthoxy)-2-hydroxypropoxy] naphthaldehyde (1) have been prepared by reaction of 2-hydroxynaphthaldehyde with 1,3-dichloro-2-propanol. new n2o3 macro-acyclic ligands (l1, l2) synthesized from the reaction of (1) with aniline or cyclohexylamine. ni (ii), co (ii) and cu (ii) complexes was prepared from reaction of schiff-bases with metal chloride and nitrate salts. all of these com...

in the present study, the cooperative and diminutive interplay between halogen, hydride, and cation-σ interactions are studied in hmgh···li+(na+)···nccl, li+(na+)···hmgh···clcn and hmgh···clcn···li+(na+) complexes by means of ab initio calculations. to better understand the cooperative or diminutive effects in the ternary systems, the corresponding binary complexes are also considered. the esti...

AbstractThe ability of hesperidin (HP) to form complexes with five metals; cobalt, nickel, zinc, calcium and magnesium was investigated. The complexation was studied using U.V spectroscopic titration, in methanol as well as aqueous buffer solutions (physiological conditions). Potential complexes were studied by IR and NMR spectroscopy, melting point and their solubility were also evaluated. The...