Electrocatalytic CO2 reduction to CO was achieved with a novel Mn complex, fac-[MnBr(4,4'-bis(phosphonic acid)-2,2'-bipyridine)(CO)3 ] (MnP), immobilized on a mesoporous TiO2 electrode. A benchmark turnover number of 112±17 was attained with these TiO2 |MnP electrodes after 2 h electrolysis. Post-catalysis IR spectroscopy demonstrated that the molecular structure of the MnP catalyst was retaine...

Uniform and pinhole-free electron-selective TiO2 layers are of utmost importance for efficient perovskite solar cells. Here we used a scalable and low-cost dip-coating method to prepare uniform and ultrathin (5-50 nm) compact TiO2 films on fluorine-doped tin oxide (FTO) glass substrates. The thickness of the film was tuned by changing the TiCl4 precursor concentration. The formed TiO2 follows t...

The present study seeks to investigate the capacity of polyaniline/titanium dioxide (PAn/TiO2) and Polypyrrole/titanium dioxide (PPy/TiO2) nano-adsorbents to adsorb Congo red anionic dye (CR) from aqueous solution. The variables effective in CR adsorption, including adsorbent dose, pH of the solution, contact time, initial dye concentration, and temperature were examined. The study yielded the ...

adsorption capacity of 4-chloro-2-nitrophenol (4c2np) onto nano-ti02 from aqueous solutions wasinvestigated in a batch system by considering the effects of various parameters like contact time, nano-tio2 dosage, initial ph and initial 4c2np concentration. optimum conditions for 4c2np adsorptionwere found to be initial ph z 2, nano-tio2 closer- 0.01 g and equilibrium time 1 h. the adsorptionkine...

Due to the dynamic nature and low stoichiometry of protein phosphorylation, enrichment of phosphorylated peptides from proteolytic mixtures is often necessary prior to their characterization by mass spectrometry. Several phosphopeptide isolation strategies have been presented in the literature, including immobilized metal ion affinity chromatography. However, that technique suffers from poor se...

[Abstract] In order to fabricate new dye-sensitised solar cell, we proposed a new photoresponsive electrode structure using bio nano process. Carbon nanotube-TiO2 hybrid materials having multitudious nano-sclae cavities were realized using a bifunctional cage-shaped protein possessing carbonaceous material-binding peptides and Ti-binding peptides. The obtained structure was confirmed to consist...

The nanotechnology industry is growing rapidly, leading to concerns about the potential ecological consequences of the release of engineered nanomaterials (ENMs) to the environment. One challenge of assessing the ecological risks of ENMs is the incredible diversity of ENMs currently available and the rapid pace at which new ENMs are being developed. High-throughput screening (HTS) is a popular ...

mixed-addenda vanadium substituted polyoxometalate supported on anatase tio2 crushed nano leaf was synthesized by an unusual reaction with titanium tetraisopropoxide at 100 ºc via sol–gel method under oil-bath condition. the materials characterized by xrd, tem,  ir and uv–vis  techniques.  in  the  present  work,  efficient  oxidative  of  thiols  with  polyoxometalate-tio2/hydrogen  peroxide  ...

cotton/polyester knitted fabrics as a major production of textile industry was treated with titanium dioxide nanosized particles. the treated fabric with nanosized tio2 became whiter with a good self-cleaning property. also the discoloration of reactive black 5 dye was studied and reported. the stabilization of tio2 on cotton/polyester knitted fabrics by citric acid (ca) with sodium hypophospha...