The modes of action of the commercial solvent extractants used in extractive hydrometallurgy are classified according to whether the recovery process involves the transport of metal cations, M(n+), metalate anions, MXx(n-), or metal salts, MXx into a water-immiscible solvent. Well-established principles of coordination chemistry provide an explanation for the remarkable strengths and selectivit...

In the study, a numerical simulation of sliding properties rough and smooth surfaces with micro-structure was made. The shear flow in micro-channel performed ANSYS FLUENT software. 3-D two-phase is simulated by choosing volume fluid model. CFD analysis, water air consist two immiscible phases. calculations, if first second fluid, adjustments are At beginning channel considered to be completely ...

In the study of non-equilibrium heat transfer in multiphase flow in porous media, parameters and constitutive relations, like heat transfer coefficients between phases, are unknown. In order to study the temperature development of a relatively hot invading immiscible non-wetting fluid and, ultimately, approximate heat transfer coefficients, a transparent micro-model is used as an artificial por...

Micropore membranes have been used to form arrays of microinterfaces between immiscible electrolyte solutions (µITIES) as a basis for the sensing of non-redox-active ions. Implementation of stripping voltammetry as a sensing method at these arrays of µITIES was applied recently to detect drugs and biomolecules at low concentrations. The present study uses computational simulation to investigate...

This paper demonstrates the enrichment of reticulocytes by centrifuging whole blood through aqueous multiphase systems (AMPSs)-immiscible phases of solutions of polymers that form step-gradients in density. The interfaces of an AMPS concentrate cells; this concentration facilitates the extraction of blood enriched for reticulocytes. AMPS enrich reticulocytes from blood from both healthy and hem...

HYPOTHESIS Aqueous citrate-stabilized gold nanoparticles (Au NPs) cannot be directly transferred from water to an immiscible organic solution using short alkyl ligands. However, Au NPs can be transferred from water to a water-organic interface if chemical and mechanical inputs are used to modify the interfacial energy and interfacial area. Ligand exchange can then take place at this interface. ...

Metastable solid solutions of Fe and Cu, which are immiscible in equilibrium, have been formed using high-energy ball milling of elemental powder mixtures. Single-phase face-centered-cubic (fee) solid solution was obtained for 0 <x<60, and body-entered-cubic (bee) solid solution for 75(x < 100. The transition from fee to bee occurred near x=70, where a mixture of fee and bee phases was obtained...

We present an effective method for simulating wall-bounded multiphase flows consisting of N (N > 2) immiscible incompressible fluids with different densities, viscosities and pairwise surface tensions. The N-phase physical formulation is based on a modified thermodynamically consistent phase field model that is more general than in a previous work, and it is developed by considering the reducti...

Two-phase partitioning bioreactors (TPPBs) consist of a cell-containing aqueous phase and an immiscible organic phase that sequesters and delivers toxic substrates to cells based on equilibrium partitioning. The immiscible organic phase, which acts as a buffer for inhibitory substrate loadings, makes it possible for TPPBs to handle high volatile organic compound (VOC) loadings, and in this stud...

Beverage emulsions are systems that are composed of two liquids including oil and water which are prepared by homogenizing oil phase in an acidic aqueous phase. They must be stable in both concentrated and diluted form for a period of 6-12 months upon standing at room temperature. Two immiscible phases contained systems are thermodynamically unstable. In other words, they are vulnerable to brea...