Interest in describing clathrate hydrate formation mechanisms spans multiple fields of science and technical applications. Here, we report findings from multiple molecular dynamics simulations of spontaneous methane clathrate hydrate nucleation and growth from fully demixed and disordered two-phase fluid systems of methane and water. Across a range of thermodynamic conditions and simulation geo...

In this work we investigated the behavior of methane hydrates dispersed in crude oils from different fields at temperatures below 0°C. In case of crude oil emulsion the size of water droplets is in the range of 50÷100μm. The size of hydrate particles formed from droplets is the same. The self-preservation is not expected in this field. However, the self-preservation of hydrates with the size of...

The present work investigates equilibrium conditions and dissociation enthalpy of hydrates formed from CO2-TBAB(tetra-n-butylammonium bromide)-water mixtures. Differential Thermal Analysis (DTA) was used for Hydrate-Liquid-Vapour (H-L-V) equilibrium condition determination in a TBAB concentration range from 4.43 to 9.01 wt% and in a CO2 pressure range from 0.3 to 2.5 MPa. The results showed tha...

In this simulation study, we analyzed the geomechanical response of two known Class 3 permafrost deposits: the Mallik (Northwest Territories, Canada) deposit and Mount Elbert (Alaska, USA) deposit. Gas was produced from these deposits at constant pressure using horizontal wells placed at the top of the hydrate layer (HL). The depressurization-induced dissociation begins at the well bore, and th...

Gas Hydrates are widely distributed in the near surface at high latitudes and many ocean bottoms. Our laboratory measurements help calibrate the seismic and well log data that are used to ascertain the in situ distribution of hydrates. Ultrasonic velocities are measured in unconsolidated sand specimen under thermobaric conditions comparable to those found in shallow oceanic or permafrost region...

Hydrate-bearing sediment cores were retrieved from the Joetsu Basin (off Joetsu city, Niigata Prefecture) at the eastern margin of the Japan Sea during the MD179 gas hydrates cruise onboard R/V Marion Dufresne in June 2010. We measured molecular and stable isotope compositions of volatiles bound in the gas hydrates and headspace gases obtained from sediments to clarify how the minor components ...

We present a model of the global methane inventory as hydrate and bubbles below the sea floor. The model predicts the inventory of CH(4) in the ocean today to be approximately 1600-2,000 Pg of C. Most of the hydrate in the model is in the Pacific, in large part because lower oxygen levels enhance the preservation of organic carbon. Because the oxygen concentration today may be different from th...

The objectives of coring and downhole logging at this site are tied to completing the transect of scientific drill sites across the Northern Cascadia Margin to further constrain models for the formation of marine gas hydrate in a subduction zone acretionary prism. The depth to the BSR rapidly becomes shallower around this site and is only half the depth (~125 mbsf) than at Site U1327 (~225) mbs...

We use the TOUGH+HYDRATE code to assess the production potential of challenging hydrate deposits, i.e., deposits that are characterized by any combination of the following factors: absence of confining boundaries, high thermodynamic stability, low temperatures, low formation permeability. Using high-resolution grids, we show that a new horizontal well design using thermal stimulation coupled wi...

Seafloor methane release due to the thermal dissociation of gas hydrates is pervasive across the continental margins of the Arctic Ocean. Furthermore, there is increasing awareness that shallow hydrate-related methane seeps have appeared due to enhanced warming of Arctic Ocean bottom water during the last century. Although it has been argued that a gas hydrate gun could trigger abrupt climate c...