C288 this compound is crystallized from solutions in acethophenone as a host-guest complex with a ratio 2:3. In the crystal structure DEDA molecules form infinite chains in a direction [01-1] through a pair of centrosymmetric hydrogen bonds. The acethophenone molecules are situated inside different channels formed at stacking of these chains and running along [100] and [0-11] directions. At dec...

The structural geometries of cucurbit[n]uril CB[n] with n = 6–9 and their complexes oseltamivir (OST) drug were obtained using the density functional theory computations. stationary points most stable confirmed vibrational frequency calculation. complexation energies electronic properties CB[n]/OST investigated. calculated results indicate that intermolecular interactions in all studied occur v...

QEMU [1] is a system emulator that can run unmodified guest operating systems on a host OS, where the guest and host CPU architecture can be different. For example, QEMU can run x86 guest OSes on a MIPS host, or even x86 on x86 (e.g., a Windows guest on a Linux host). QEMU emulates a complete system including processors, devices, and chipsets. More implementation details regarding QEMU are avai...

Nanostructured materials have become the central subject of materials research during the last decade in the past 20th century owing to the novel electronic, optical, and catalytic properties observed in such materials. The unusual properties of these nanostructured materials can be attributed to two main microscopic effects: quantum confinement and electronic confinement. These two effects hav...

This paper presents the synthesis, the structural determination and the sensing capabilities toward Volatile Organic Compounds (VOCs) of a new class of fluorescent indolizine-cyclodextrin sensors. Two different pathways, both involving bipyridinium ylides and 6-amino-b-cyclodextrin, have been used to carry out the synthesis of these sensors. The macrocycle structures were dominantly established...

An anhydrous 1:1 crystalline inclusion complex between the organophosphorus insecticide fenitrothion [O,O-dimethyl O-(3-methyl-4-nitrophenyl)phosphorothioate] and the host compound heptakis(2,6-di-O-methyl)-β-cyclodextrin (DIMEB) was prepared and its structure elucidated by single-crystal X-ray diffraction. This revealed two independent host molecules in the asymmetric unit. In one of these, th...

Conspectus This Account focuses on stimuli responsive systems that function in aqueous solution using examples drawn from the work of the Isaacs group using cucurbit[n]uril (CB[n]) molecular containers as key recognition elements. Our entry into the area of stimuli responsive systems began with the preparation of glycoluril derived molecular clips that efficiently distinguish between self and n...

      A novel podand based anion receptor bearing benzimidazole motifs as recognition sites was designed and synthesized by reaction of 1,7-bis(2'-methylbenzoate)-1,4,7-trioxaheptane and phenylenediamine. The binding properties of anionic guest with this receptor were studied using UV-Vis and fluorescence spectroscopy. These studies revealed that this receptor exhibit selective recognition towar...

The use of mammalian cells for therapeutic applications is finding its way into modern medicine. However, modification or "training" of cells to make them suitable for a specific application remains complex. By envisioning a chemical toolbox that enables specific, but straight-forward and generic cellular functionalization, we investigated how membrane-receptor (pre)targeting could be combined ...

The self-assembly of 2,4,6-tris(pyridin-4-yl)-1,3,5-triazine (tpt) triangular panels with p-cymene-ruthenium building blocks and 5,8-dioxido-1,4-naphthoquinonato (donq) bridges, in the presence of pyrenyl-containing dendrimers of different generations (P(0), P(1) and P(2)), affords the triangular prismatic host-guest compounds [P(n)⊂Ru(6)(p-cymene)(6)(tpt)(2)(donq)(3)](6+) ([P(n)⊂1](6+)). The h...