Supercritical fluid extraction (SFE) provides an environmentally green technique to decontaminate chromium species from solid matrices using supercritical fluid carbon dioxide (ScCO2). Methanol and a small amount of water were found to significantly improve the extraction efficiency. The fluorinated chelating agent lithium bis(trifluoroethyl)-dithiocarbamate (LiFDDC) was effective in removing C...

It is shown that during electron beam sintering in the forevacuum pressure region of powder components composite Al 2 O 3 -Cr ceramics, magnitude current flowing through sample depends both on percentage chromium and heating temperature sample. When a certain reached, process flow influenced by thermoelectric emission from surface. Along with ions plasma, noticeable contributes to neutralizing ...

The knowledge of Cr2O3 activity in slag is necessary to decarburize chromium-containing special steel while minimizing the oxidation loss chromium. In present study, firstly, phase relationship CaO–SiO2–Cr2O3 system was determined at 1573 K. Subsequently, activities two- and three-phase coexisting slags K were measured by equilibrating molten copper with oxide phases under a stream Ar + H2 CO2 ...

The gradual elimination of chromium from wood preservative formulations results in higher Cu leaching and increased susceptibility to wood decay fungi. Finding a sustainable strategy in wood protection has become of great interest among researchers. The objective of these in vitro studies was to demonstrate the effect of T-720-enriched organic charcoal (biochar) against five wood decay basidiom...

T H E value of chromic oxide (chromium sesquioxide) as an indicator for estimating fecal output of sheep and cattle is dependent upon its concentration at a given sampling time providing the basis for estimating a standard recovery. However, chromic oxide excretion rate exhibits a diurnal variation (Hardison et al., 1959; Kane, Jacobson and Moore, 1952) which apparently precludes choosing a des...

Aqueous plant leaves extract (PLE) of an abundant shrub, Sorbaria sorbifolia, was explored for the reduction of hexavalent chromium, Cr(VI), to trivalent chromium, Cr(III). The effect of contact time, pH, PLE quantity, ionic strength, hardness, temperature and effective initial Cr(VI) ion concentration were tested; Cr(VI) reduction followed the pseudo-first order rate kinetics and maximum reduc...

The present paper investigates to examine the in vitro antibacterial activities of the chromium nanopartical which preparied by -green synthesis techniquesreduction of potassium dichromate solution with Arachis hypogaea leaf extract containing reducing sugars which act as reducing agent. Chromium nanoparticles were shown to be an effective control of two phytopathogenic bacteria, namely Erwinia...

I The continuous faecal marker chromic oxide, Cr,O,, and the intermittent marker brilliant blue were used together in metabolic balance studies of calcium and magnesium in two young women. 2. Faecal output was derived by four methods: no marker, brilliant blue, Cr,Os, or both brilliant blue and Cr,Os. 3. Balances of Ca and Mg derived by the four methods of obtaining faecal output were compared....

Background & objectives: The import of heavy metals into various sources of drinking water supply is one of the major problems of water quality, especially in industrial areas. The aim of this study was to investigate the ability of mercury and arsenic metal pollutants to be removed from aqueous solutions using green oxide nanoparticles synthesized by green method. For this purpose, the extract...

The very thin native oxide film on stainless steel, of the order of 2 nm, is known to be readily modified by immersion in aqueous media. In this paper, XPS and ToF-SIMS are employed to investigate the nature of the air-formed film and modification after water emmersion. The film is described in terms of oxide, hydroxide and water content. The preferential dissolution of iron is shown to occur o...