نتایج جستجو برای: glycoside
تعداد نتایج: 5502 فیلتر نتایج به سال:
Four new triterpene glycosides: one cycloartane-type glycoside and three azukisapogenol glycosides were isolated together with one known oleanene bisdesmoside from the Mongolian natural medicine, Oxytropis myriophylla.
A new acylated flavonol glycoside was isolated from the leaves of Eriobotrya japonica along with two known flavonol glycosides. Their structures were determined by extensive spectroscopic investigation.
Glycoproteins are ubiquitous in nature and fundamental to most biological processes, including the human immune system. The glycoprotein carbohydrate moieties, or glycans, are very diverse in their structure and composition, and have major effects on the chemical, physical and biological properties of these glycoproteins. The hydrolysis of glycoprotein glycans by bacterial glycosidases can have...
Activity-based protein profiling has emerged as a powerful tool for visualizing glycosidases in complex biological samples. Several configurational cyclophellitol isomers have been shown to display high selectivity as probes for glycosidases processing substrates featuring the same configuration. Here, a set of deoxygenated cyclophellitols are presented which enable inter-class profiling of β-g...
L-DMDP and L-homoDMDP, the enantiomers of naturally occurring DMDP and homoDMDP have been synthesized from D-xylose derived cyclic nitrone 9. Their 3-deoxy-3-fluorinated analogues were also obtained from polyhydroxylated fluorinated cyclic nitrone 10, which was prepared from fluorinated sugar 12 in seven steps. Bioactivities of these iminosugars against various glycosidases were evaluated. Whil...
The Structural Genomics Initiative promises to deliver between 10,000 and 20,000 new protein structures within the next ten years. One challenge will be to predict the functions of these proteins from their structures. Since the newly solved structures will be enriched in proteins with little sequence identity to those whose structures are known, new methods for predicting function will be requ...
There is little known about the nature of the metabolic products derived from cardiac glycosides in the animal body. Reports of the formation of digitoxigenin from the glycoside digitoxin in vivo have appeared in the literature (l-3), but reliable chemical methods of identification applicable to the very small quantities of material involved were not available to these workers. Fischer, Sjoerds...
Two O-hydroxylysyl glycosides, Hyl-Gal-Glc and Hyl-Gal, have been isolated from normal human urine and shown to be identical to two glycosides isolated from alkaline hydrolysates of collagen. A relatively sample and reproducible analytical procedure has been devised to measure the levels of these glycosides in human urine. By the use of this procedure it was shown that a normal diet has only a ...
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