to improve the corrosion protection of copper metal, 0.01m concentration of 1h-1,2,4-triazole-3-thiol (tat) was incorporated into the hybrid sol-gel monolayers containing 3-glycidoxypropyltrimethoxysilane (gptms) and tetraethoxysilane (teos). it was further subjected to hydrolysis and condensation reaction to form a sol-gel matrix. the tat-doped hybrid sol-gel coating was applied over the coppe...

in this study, an extended stress-based forming limit diagram (fld) for prediction of necking based on the marciniak and kucznski (m-k) model is represented and applied in tube hydroforming. the bulge forming of a straight tube is simulated by finite element method and verified with published experimental data. this adaptive simulation technique is based on the ability to detect the onset and g...

We investigate the gel formation from the equilibrium sol phase in a simple model that has the characteristics of (colloidal) gel-forming systems at a finite temperature. At low volume fraction and low temperatures, particles are linked by long-living bonds and form an open percolating network. By means of molecular dynamics simulations, we study the lifetime of bonds and nodes of the gel netwo...