Large scale synthesis of uniform self-assembly Fe(3)O(4)@phenol formaldehyde resin (PFR) core-shell nanowires with 80-100 nm in diameter and 20-30 microm in length can be realized by a one-pot hydrothermal process. The optical and magnetic properties of the as-synthesized Fe(3)O(4) nanostructures have been investigated.

Vehicular emission (VE) is one of the important anthropogenic sources for airborne carbonyls in urban area. Six types of VE-dominated samples were collected at representative locations in Hong Kong where polluted by a particular fueled type of vehicles, including (i) a gas refilling taxis station (liquefied petroleum gas [LPG] emission); (ii) a light-duty passenger car park (gasoline emission);...

This study was aimed at determining the effect, if any, that steric factors may have on the diastereoselectivity in the spiroannulation of simple phenols. A series of phenols bearing different size substituents ortho to the phenolic hydroxyl were synthesized and spiroannulated to the corresponding spiroethers in good to excellent yields (76-94%). However, the diastereoselectivity of the reactio...

Pyrolysis of phenolic resins leads to carbon formation. Simulating this resin-to-carbon process atomistically is a daunting task. In this paper, we attempt to model the initial stage of this process by using the ReaxFF reactive force field, which bridges quantum mechanical and molecular mechanical methods. We run molecular dynamics simulations to examine the evolution of small molecules at diff...

Key Laboratory of Chemistry in Ethnic Medicinal Resources, State Ethnic Affairs Commission & Ministry of Education, Yunnan University of Nationalities, Kunming 650031, P. R. China *E-mail: [email protected] (Q.-F. Hu); [email protected] (X. Li) Key Laboratory of Tobacco Chemistry of Yunnan Province, Yunnan Academy of Tobacco Science, Kunming 650106, P. R. China Received February 6, 2012, Accepte...

Hydrolysis of cyanuric acid, melamine, melem, atrazine and melamine-formaldehyde resin was found to be catalyzed by an A1203 catalyst. The reactions occur irreversibly with cleavage of the s-triazine ring between 240 and 450°C. The s-triazine-ring is hydrolyzed to ammonia and carbon dioxide, and the substituted groups to the corresponding molecules by addition of hydrogen.