A review of the literature about calculating the adsorption properties of arsenic onto mineral models using density functional theory (DFT) is presented. Furthermore, this work presents DFT results that show the effect of model charge, hydration, oxidation state, and DFT method on the structures and adsorption energies for As and As onto Fe-(oxyhydr)oxide cluster models. Calculated interatomic ...

Economically important manganese deposits are hosted in the Middle Permian Maokou Formation of Zunyi, northern Guizhou, South China. During Permian, intense rifting related to initial stage Emeishan Large Igneous Province (ELIP) led development carbonate platforms and inter-platform troughs. The occur transitional zone between Previous studies emphasized that hydrothermal activities at bottom t...

Switchable surface redox chemistry is demonstrated in gold@iron/iron oxide core-shell nanoparticles with ambient oxidation and plasmon-mediated reduction to modulate the oxidation state of shell layers. The iron shell can be oxidized to iron oxide through ambient oxidation, leading to an enhancement and red-shift of the gold surface plasmon resonance (SPR). This enhanced gold SPR can drive redu...

In order to reveal the formation mechanism of different garnets and its implications for fluid evolution in Laoshankou Fe-Cu-Au deposit northern margin East Junggar (NW China), three types garnet have been investigated detail this study. (1) Type 1 grossular, formed at Ca-silicate stage (stage I, pre-mineralization stage), was replaced by 2 magnetite, displays a compositional range Grs44–53Adr4...

The stimulation of subsurface microbial metabolism often associated with engineered bioremediation of groundwater contaminants presents subsurface microorganisms, which are adapted for slow growth and metabolism in the subsurface, with new selective pressures. In order to better understand how Geobacter species might adapt to selective pressure for faster metal reduction in the subsurface, Geob...

biogeochemistry is a useful tool for assessing geochemical dispersion patterns. sari gunay epithermal gold deposit was selected in order to assess the application of biogeochemical exploration for gold in northwestern iran. in this study, four sites were sampled in a profile perpendicular to mineralized vein with a control site two km far-off mineralized vein. a sample from each dominant plant ...

introduction: acute renal failure is a common consequence of sepisis due to concurrent renal ischaemia. the role of nitric oxide (no) in endotoxaemia and in ischaemic injury in the kidney is not well defined. material and methods: in this study we have used an animal model of sepsis induced by injection of bacterial lipopolysaccharide (lps) in the rat and measured renal nitric oxide by x-band e...