Tree fern, an agricultural by-product, was used for the sorptive removal of copper ions from aqueous solution. The experimental data was analysed by Langmuir, Freundlich and Redlich-Peterson isotherms. The equilibrium sorption capacity of copper ions was determined from the Langmuir equation and found to be 11.7 mg/g. A batch sorption model, based on the assumption of the pseudo-second-order me...

The aim of this study is to investigate the possibility of Saccharomyces cerevisiae as an alternative adsorbent for phenol removal from aqueous solution .The Saccharomyces cerevisiae was characterised by Brunauer Emmett Teller (BET) and Fourier transform (FT-IR). Adsorption properties of Saccharomyces cerevisiae towards phenol were systematically investigated, including pH effect, adsorbent dos...

For a multicomponent competitive adsorption of furfural and phenolic compounds, a mathematical model was builtto describe the mass transfer kinetics in a fixed bed column with activated carbon. The effects of competitive adsorption equilibrium constant, axial dispersion, external mass transfer, and intraparticle diffusion resistance on the breakthrough curve were studied for weakly adsorbed com...

In the present work, the usefulness of dried activated sludge has been investigated for the removal of copper ions from aqueous solutions. Kinetic data and equilibrium sorption isotherms were measured in batch conditions. The influence of initial pH, metal concentration and copper salt nature on the metal removal kinetics has been studied. Copper uptake was time contact, initial copper concentr...

Tropomyosin is a coiled-coil protein that polymerizes by head-to-tail interactions in an ionic strength-dependent manner. We produced a recombinant full-length chicken alpha-tropomyosin containing a 5-hydroxytryptophan residue at position 269 (formerly an alanine), 15 residues from the C terminus, and show that its fluorescence intensity specifically reports tropomyosin head-to-tail interaction...

The present study presents the effective use of nanocrystalline akaganeite for the adsorption of an anionic (SDS), a cationic (CTAB), and a nonionic (tween80) surfactant from wastewater. Equilibrium experiments, as well as thermodynamic analysis, were performed. The maximum SDS adsorption occurs at the lowest pH value (5), the opposite is observed for CTAB (pH = 11), while for tween80, the chan...

The performance of activated sludge in the removal of tetradecyl benzyl dimethyl ammonium chloride (C14BDMA) by adsorption from aqueous solution was investigated with different PH, contact time, ionic strength and temperature. Equilibrium was achieved within 2 h of contact time. The adsorption capacity increased largely with increasing solution pH and remained constant above pH 9. The ionic str...

Adsorption of Congo red (CR) from aqueous solution using dried roots of Eichhornia crassipes was studied. Batch experiments were carried out for sorption kinetics and isotherms. Experimental results obtained showed that adsorption process was highly dependent on contact time, adsorbent dosage, initial dye concentration and particle size. The sorption equilibrium for Congo red dye by E. crassipe...

Polyacrylonitrile (PAN)-oxime-nano Fe2O3 was used as an adsorbent for the removal of fluoride from water. The influences of contact time, initial fluoride concentration, and adsorbent dosage were investigated by batch equilibrium studies. The rate of adsorption was rapid with equilibrium being attained after 100min. The Langmuir isotherm model was found to represent the measured adsorption data...

We study by using Monte Carlo simulations the hysteresis in unzipping and rezipping of a double stranded DNA (dsDNA) by pulling its strands in opposite directions in the fixed force ensemble. The force is increased at a constant rate from an initial value g(0) to some maximum value g(m) that lies above the phase boundary and then decreased back again to g(0). We observed hysteresis during a com...