In this article, we developed a facile one-step hydrothermal method using dimethyl formamide (DMF) as a reducing agent for the fabrication of PdAg catalyst. The scanning electron microscope (SEM) and transmission electron microscopy (TEM) images have shown that the as-synthesized PdAg catalyst had a nanochain structure. The energy-dispersive X-ray analyzer (EDX) spectrum presented the actual mo...

A hybrid ultramicroelectrode containing one micro-carbon electrode and one empty micro-channel was employed to be a micro-electrochemical cell and a mass spectrometric nanospray emitter. This setup can combine MS with an electrode directly and provide in situ information about an electrochemical reaction. The mechanisms proposed by Bard et al. for a Ru(bpy)32+ (bpy = 2,2'-bipyridine) electroche...

I evaluated a commercial electrochemical method (Environmental Science Associates), based on potentiostatic coulometry, for determining iron and total iron-binding capacity (TIBC). The method requires 25 and 100 microL of serum, respectively, for these measurements. Serum iron concentrations so determined in 99 normal volunteers satisfactorily correlated with those determined by the Iron Panel ...

In this work, a nickel-modified glassy carbon electrode (GCE) was prepared using a potentiostatic method in 0.1 M acetate buffer solution at pH 4.0 containing 1.0 mM nickel nitrate. Nickel hydroxide nanoparticles were prepared using consecutive potential scanning in 0.1 M NaOH solution. The as-prepared catalyst was characterized by field emission scanning electron microscopy and electrochemical...

In this work, we reported a facile one-pot hydrothermal method to synthesize MnPO4·H2O nanowire/graphene oxide composite material with coated graphene oxide. Transmission electron microscopy and scanning electron microscope were employed to study its morphology information, and X-ray diffraction was used to study the phase and structure of the material. Additionally, X-ray photoelectron spectro...

A novel strategy for electrochemical biosensing of food pathogenic bacteria using nanostructured electrochemical magneto electrode is reported. In this approach, the bacteria are attached to magnetic beads by immunological reaction with specific antibody against Salmonella. Further amplification of the genetic material with a double-tagging set of primer is then performed and the amplicon captu...

A novel electrochemical sensing method was devised for the first time to detect plasma cortisol, a potential psychological stress biomarker, in human immunodeficiency virus (HIV)-positive subjects. A miniaturized potentiostat (reconfigured LMP91000 chip) interfaced with a microfluidic manifold containing a cortisol immunosensor was employed to demonstrate electrochemical cortisol sensing. This ...

The signal amplification technique of peptide nucleic acid (PNA)-based electrochemical DNA sensor was developed in a label-free and one-step method utilizing enzymatic catalysis. Electrochemical detection of DNA hybridization on a PNA-modified electrode is based on the change of surface charge caused by the hybridization of negatively charged DNA molecules. The negatively charged mediator, ferr...

The electrochemical activities of PbO(2) thin-film electrodes were systematically studied with an oxygen-transfer reaction, i.e., the oxidation of thiourea. Five different types of PbO(2) film electrodes were prepared using various methods to investigate the influence of the interfacial oxide layer formed between the Ti substrate and the PbO(2) layer contacting the electrolyte. Among the electr...