tabas mines in iran have coal sources which are suitable for use in metallurgy industries as coking coal. but the high sulfur content of this coal imposes severe limitations on its utilization as the sulfur oxide gases evolved from the combustion of high sulfur coals result in acid rains and corrosion of equipments. in this work, attempts have been made to reduce sulfur from high sulfur coal of...

this research was conducted to study the effect of lime based flux with the composition of cao-20%caf2-8%feo on simultaneous removal of phosphorus and sulfur from hot metal. the effects of na2o and oxygen blowing were also studied. the experiments were performed using an induction furnace and hot metal produced in isfahan steel company in the temperature range 1350-1450 ºc. the results showed t...

Synthesis of the first P(V)-bridged bis(NHC) ligand 7 was achieved via deprotonation of P(V)-functionalized bis(imidazolium) salt 6, which was obtained via oxidative desulfurization of bis(imidazole-2-thion-4-yl)phosphane 2. Bis(imidazolium) salt 6 was also employed to synthesize the corresponding silver complex 8. All new products were firmly established by spectroscopic and spectrometric meth...

An isopolyoxovanadate catalyst [C(8)H(17)N(CH(3))(3)](3)H(3)V(10)O(28) shows high catalytic activity in oxidation of dibenzothiophene (DBT) to its corresponding sulfone using molecular oxygen as oxidant under mild reaction conditions. This is potentially a promising approach to achieve ultradeep desulfurization of fuels (e.g. diesel) because the sulfones can be more conveniently removed from th...

Platinum group metals (PGMs) usually exhibit promising aerobic catalytic abilities, providing a green and feasible oxidative desulfurization method. However, often, the PGM nanoparticles (NPs) get leached, catalysts are deactivated. In this work, Pt NPs with particle sizes of approximately 4–5 nm were encapsulated effectively uniformly on surface vanadium pentoxide (V2O5) nanosheets (with thick...

the direct sulfation of three high purity iranian limestones and one precipitated calcium carbonate from different sources, containing more than 97 % caco3, were studied in a specially designed fixed bed reactor under atmospheric pressure, in the presence of excess co2 to prevent decomposition of caco3. experiments were carried out over a range of particle sizes from 1.6-2.5  mm at four tempera...