An ultrafine grain surface layer with average crystallite size of 28 nm was produced on annealed mild steel through a wire brushing process. The effects of grain size reduction on the inhibition performance of sodium phosphate were investigated using polarization and electrochemical impedance spectroscopy (EIS) measurements. The crystal grain size of wire brushed surface was analyzed by X-ray d...

The study examined corrosion inhibition of corrosion inhibition of 5-methyl-2H-imidazol-4-carboxaldehyde and 1H-Indole-3-carboxaldehyde on mild steel in acidic medium using weight loss and Density Functional Theory (DFT) methods. DFT calculations were carried out at B3LYP/6-31+G** level of theory in aqueous medium on the molecular structures to describe electronic parameters. The values of ther...

The development of a methodology to predict the performance of a corrosion inhibitor (CI) using specific types of modeled and experimental surfaces and their subsequent estimation is presented. For previously reported imidazoline CIs, the theoretical partition coefficients and molecular volumes were calculated, providing a guide for molecular engineering of new imidazolines. The new CIs, N-[2-(...

The macrocylic ligand, 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane (MHACD) was synthesized by the demetallation of its freshly synthesized Ni(II) complex (NiMHACD). Successful synthesis of NiMHACD and the free ligand (MHACD) was confirmed by various characterization techniques, including Fourier transform infra-red (FT-IR), proton nuclear magnetic resonance (¹H-NMR), carbon-13 nuclear ma...

Chrysoidine dye was examined as an inhibitor for mild steel in 1N HCl using weight loss, gasometric and thermometric methods. Parameters such as inhibition efficiency and corrosion rates were evaluated. The inhibition efficiency was found to increase with increase in the inhibitor concentration. To study the adsorption of the inhibitor on the mild steel surface, adsorption isotherm was plotted.

Corrosion inhibitory impacts of turmeric with concentrations of 200-800 ppm on the electrochemical behavior of mild steel were studied in the medium of NaCl 3.5% using several techniques such as electrochemical impedance spectroscopy (EIS) and polarization. Scanning electron microscopy (SEM) was used for analyzing the surface of mild steel after 24 hours of immersion in the electrolyte solution...

The corrosion behavior of mild steel in 0.1 M aqueous sulfuric acid medium has been studied using weight loss, potentiodynamic polarization measurements, quantum chemical calculations, and molecular dynamic simulations in the presence and absence of 4-methyl-4H-1,2,4-triazole-3-thiol and 2-mercaptonicotinic acid. Potentiodynamic measurements indicate that these compounds mostly act as mixed inh...

In this article, the corrosion inhibition of steel DIN 2391 St 37-4 in acidic medium 5% H2SO4 with and without presence eco inhibitors leaf (Petroselinum Sativum) was examined. Inhibitory properties parsley leaves on were examined by potentiodynamic polarization - Tafel extrapolation, FTIR method order to categorize oxide layer. The test performed static stirring at 600 rpm. By extrapolation ba...

This paper describes an experimental study on calcium sulphate scaling and prevention by newly treated polyacrylamide in a laboratory model. In order to study the inhibiting capacity of the chemical used, experiments were performed in solutions involving treatment of synthetic sea water with different concentrations of the polymer. Polyacrylamide gave significantly lower precipitation rate comp...