By using quantum mechanical DFT calculations, the most probable structure of the bambus[6]uril x NO3(-) anionic complex species was derived. In this complex having C3 symmetry, the nitrate anion NO3(-), included in the macrocyclic cavity, is bound by twelve weak hydrogen bonds between methine hydrogen atoms on the convex face of glycoluril units and the considered NO3(-) ion.

The effect of various salts such as magnesium nitrate, calcium nitrate, zinc nitrate, and magnesium chloride on vapor−liquid equilibrium (VLE) of the ethyl acetate−ethanol system was studied experimentally in a modified Othmer still at atmospheric pressure. The influence of cation and anion of the salts on the VLE of the ethyl acetate− ethanol system was examined. It was observed that the order...

Two new mononuclear cationic complexes in which the TbIII ion is bis-chelated by the tripodal alcohol 1,1,1-tris-(hy-droxy-meth-yl)propane (H3LEt, C6H14O3) were prepared from Tb(NO3)3·5H2O and had their crystal and mol-ecular structures solved by single-crystal X-ray diffraction analysis after data collection at 100 K. Both products were isolated in reasonable yields from the same reaction mixt...

Mononuclear mixed-anions Mn complex of TPAMn(η-NO3)(η-ClO4), where TPA is tris(2-pyridylmethyl)amine, has been synthesized and characterized. The neutral TPAMn(η-NO3)(η-ClO4) was obtained from the reaction between Mn(NO3)2·4H2O and [H3TPA](ClO4)3 in MeOH. X-ray crystallographic structure of mononuclear TPAMn(η-NO3)(η-ClO4) complex showed a seven-coordinated geometry with a tripodal tetradentate...

Root development is extremely sensitive to variations in nutrient supply, but the mechanisms are poorly understood. We have investigated the processes by which nitrate (NO3-), depending on its availability and distribution, can have both positive and negative effects on the development and growth of lateral roots. When Arabidopsis roots were exposed to a locally concentrated supply of NO3- ther...

Previous studies on the effects of land cover influence on stream nitrogen have focused on base flow conditions or were conducted specifically within urbanized or primarily agricultural watersheds. While these studies have shown relationships between land cover and nitrogen, this relationship and the scale of influence could change during storms. The purpose of my study was to understand how la...

BACKGROUND Nitrite (NO2-) and nitrate (NO3-) contaminations of groundwater are considered as one of the major health challenges in recent decades. This study aimed to evaluate the nitrite and nitrate concentrations in the drinking groundwater of Shiraz, South-central Iran by statistical models. METHODS From 43 active wells of Shiraz drinking water supplies, 344 samples were collected in the h...

to study the spatial and temporal variation of nitrate pollution in groundwater in the vicinity of zayandehrud river in isfahan province monthly water samples were collected from 100 wells in the study area. the average n03-n concentration ranged from 1.2 to 25.7 mg/l (5.4 to 115.6 mg/i as no3) and average n03-n concentration in groundwater was 9.6 mg/i, which is lower than the standard limit (...

[1] Nitrate (NO3 ) concentrations and dual isotopic composition (dN and dO) were measured during various seasons and tidal conditions in Elkhorn Slough to evaluate mixing of sources of NO3 within this California estuary. We found the isotopic composition of NO3 was influenced most heavily by mixing of two primary sources with unique isotopic signatures, a marine (Monterey Bay) and terrestrial a...

The ecological prominence of diatoms in the ocean environment largely results from their superior competitive ability for dissolved nitrate (NO3-). To investigate the cellular and genetic basis of diatom NO3- assimilation, we generated a knockout in the nitrate reductase gene (NR-KO) of the model pennate diatom Phaeodactylum tricornutum In NR-KO cells, N-assimilation was abolished although NO3-...