nano silica-h2so4 is an efficient and mild catalysis system for the regeneration of aldehyde from aldoximes. ketoximes are converted to amides by beckmann rearrangement in the presence of nano silica-h2so4. the reactions are carried out in solvent-free conditions under microwave irradiation (600 w) within 50-120 sec in good yields.

cyanobacteria are well known for their production of a multitude of highly toxic substances . the genus stigomena is regarded as good candidates for producing biologically active secondary metabolites, which are highly toxic to humans and other animals. the carcass of a dog was found at the shore of lake ali-abad, iran. biomass from the discovery site appeared to be of cyanobacterial nature. we...

Many different compound semiconductors can be formed by changing the combination of constituent elements. Properties of alloy semiconductors composed of a plurality of compound semiconductors can be changed in a continuous fashion by changing the composition ratio. A very thin alloy semiconductor multilayer showing interesting properties can be formed by sophisticated epitaxial growth methods s...

The generation of natural product-like compound collections has become an important area of research due to low hit rates found with synthetic high-throughput libraries. One method of generating compounds occupying the areas of chemical space not accessible to synthetic planar heterocyclic structures is the utilization of natural products as starting materials. In the current work, using a ring...

"VOC emissions from beef feedlot pen surfaces as affected by within-pen location, moisture and temperature" (2015). Air quality Feedlot Gas chromatography Odour VOC A laboratory study was conducted to evaluate the effects of pen location, moisture, and temperature on emissions of volatile organic compounds (VOC) from surface materials obtained from feedlot pens where beef cattle were fed a diet...

An inorganic materials database system, AtomWork, has been developed and released on the Internet. It includes the phase diagram, crystal structure, X-ray powder diffraction, and property data of more than 80,000 inorganic materials extracted from scientific literature. The feature of this database is that the information of the synthesis, identification, and property of materials is organicall...

Bulk B-C-N materials were synthesized under static high thermobaric conditions (20 GPa and 2,000 °C) in a multianvil apparatus from a polymer derived t-BC1.97N ceramic. The bulk samples were characterised using X-ray synchrotron radiation and analytical transmission electron microscopy in combination with electron energy loss spectroscopy. Polycrystalline B-C-N materials with a cubic type struc...

A signi®cant breakthrough has been achieved using materials databases, semi-empirical methods and neural networks to aid in the design of new materials. A collaborative, international, team discovered that a non-linear expression involving one elemental property parameter could be used to predict, with 99+% accuracy, the occurrence of a compound for any ternary materials system. This elemental ...

aquatics are a source of bioactive compounds that these compounds have different properties such as antimicrobial activity. in this study, antibacterial activity of methanol, chloroform and hexane extracts from body wall, gonad and intestine of sea cucumber holothuria leucospilota was evaluated against bacillus subtilis, pseudomonas aeruginosa and staphylococcus aureus. bioactive compounds of b...

background: the antioxidant components have been identified in some pine species. antioxidant properties of proantocyanidins reduce free radicals induced by dna fragmentation and lipid proxidation and also proanthocyanidines could curb lipid peroxidation. objective: in this study, we analyzed different parts of pinus eldarica (bark, seed and needle) and assessed their antioxidant contents. meth...