Water splitting catalysed by earth-abundant materials is pivotal for global-scale production of non-fossil fuels, yet our understanding of the active catalyst structure and reactivity is still insufficient. Here we report on the structurally reversible evolution of crystalline Co3O4 electrocatalysts during oxygen evolution reaction identified using advanced in situ X-ray techniques. At electrod...

A fast, reliable, accurate, precise and sensitive pH sensor device is highly demanding for the monitoring of pH in biological, clinical and food industry samples. In this research work, the effect of anions on the morphology of cobalt oxide (Co3O4) nanostructures is investigated using low temperature chemical approach for the growth. Different anions have shown visible effect on the morphology ...

MnO2 and Co3O4 are identified as two highly MW active catalysts for the degradation and eventual mineralization of trace amounts of the toxic pollutant dye IC in water. The degradation is much faster compared to identical conventional heating conditions suggesting that the MW effect is not just thermal. ‘Specific effects’ and ‘athermal effects’ of MW also contribute to the degradation of the po...

Highly sensitive, selective, reliable and inexpensive cholesterol biosensors are highly demanded for the routine monitoring of cholesterol molecules in order to prevent the heart failure incidents. In this study, Co3O4 nanostructures are synthesized using polyvinyl pyrrolidone surfactant as a growth template by a low temperature aqueous chemical growth method. The morphology of nanostructures w...

The use of transition metals as bifunctional catalysts for rechargeable zinc-air batteries has recently attracted much attention. Due to their multiple chemical valence states, the cobalt oxides are considered be promising oxygen reduction reaction (ORR) and evolution (OER). In this work, Ag-decorated Co3O4-nitrogen doped porous carbon composite (Co3O4-NC&Ag) were synthesized by annealing Z...

Co3O4/NiO@GQDs@SO3H nanocatalyst has been used as an effective catalyst for the preparation of benzopyranopyridines through a four-component reaction of salicylaldehydes, thiols and 2 equiv of malononitrile under reflux condition in ethanol. The catalyst has been characterized by FT-IR, XRD, SEM, EDS, BET, XPS, TGA and VSM. Atom economy, reusable catalyst, low catalyst loading, applicability to...

In this research work, we report a simple method called reflux condensation method for synthesizing Co3O4 nanoparticles using cheap chemicals such as, cobalt acetate (precursor salt), sodium monododecyl sulphate - SDS (surfactant) and N, N - Dimethylformamide - DMF (solvent). The prepared materials were heat treated at 200, 400, 600 and 800 oC for each 2 h to get phase pure product. The calcine...

In this study, spinel-type cobalt oxide (Co3O4) and Co3-xDyxO4 (x = 0.04 and 0.05 molar ratio) nanoparticles were synthesized via combustion method at 700 °C. Crystallite nature, phase purity and thermal analysis of the prepared compounds were investigated by PXRD, FT-IR and TGA techniques. Structural analyses were performed by the FullProf program employing profile matching with constant scale...