Atmospheric CO2 concentrations continue to rise rapidly in response to increased combustion of fossil fuels, contributing to global climate change. In order to mitigate the effects of global warming, development of new materials for cost-effective and energy-efficient CO2 capture is critically important. Graphene-based porous materials are an emerging class of solid adsorbents for selectively r...

The main objective of this study is to investigate the feasibility and costs of ionic liquid (IL)-based CO2 capture systems at pulverized coal-fired (PC) power plants. The IL selected for this assessment is trihexyl(tetradecyl)phosphonium 2-cyanopyrrolide ([P66614][2-CNpyr]), achieving a 1:1 and reversible chemical reaction between [2-CNpyr] and CO2. A multi-stage equilibrium-based modeling fra...

Metallic catalysts are capable of designing multifunctional for efficient CO2−ODP reaction owing to their high abilities C−H scission, CO2 capture/activation, and coke removal. In this review, the catalyst design concepts metallic materials recent developments in summarized, categorizing them as monometallic, bimetallic multimetallic materials.

The biological flux and lifetime of methanol in anoxic marine sediments are largely unknown. We herein reported, for the first time, quantitative methanol removal rates in subsurface sediments. Anaerobic incubation experiments with radiotracers showed high rates of microbial methanol consumption. Notably, methanol oxidation to CO2 surpassed methanol assimilation and methanogenesis from CO2/H2 a...

Spherical MgO nanoparticles and Flake-like clay minerals modified with polyaniline (PAni) are applied in Matrimid in order to fabricate mixed matrix membranes (MMMs) having improved gas separation performance. The CO2 permeability, CO2/CH4 selectivity and CO2-induced plasticization pressure of MMMs are assessed at 4-30 bar feed pressure. The chemical structure, morphology and thermal properties...

Acid gas removal from gaseous streams such as flue gas, natural and biogas is mainly performed by chemical absorption with amines, but the process highly energy intensive can generate emissions of harmful compounds to atmosphere. Considering emerging interest in carbon capture, associated increasing environmental concerns, there much current effort develop innovative solvents able lower impact ...