نتایج جستجو برای: co oxidation
تعداد نتایج: 442113 فیلتر نتایج به سال:
Cerium nanopowders doped by a small amount of silver exhibit interesting catalytic properties towards the low temperature oxidation of CO. It is generally believed that a metal support interaction plays an important role in a catalytic process. Therefore in our study we examined electronic and adsorption properties of cerium deposited onto a polycrystalline silver substrate. Layers of approxima...
Transitional metal nanoparticles or atoms deposited on appropriate substrates can lead to highly economical, efficient, and selective catalysis. One of the greatest challenges is to control the electronic metal-support interactions (EMSI) between the supported metal atoms and the substrate so as to optimize their catalytic performance. Here, from first-principles calculations, we show that an o...
Cobalt(ll) and gold(lll) react with 2,4-dihydroxy acetophenone oxime (RPO) formi ng yellowish brown and greyish green coloured soluble complexes respectively. The reactions are very slow but become fast in the presence of K2SPxThis may be due to the enhancement of aerial oxidation of metal complexes wi th RPO in their lower oxidation states (Co(! I), Au( III )) to coloured complexes with higher...
The CO oxidation behaviors on single Au atom embedded in two-dimensional h-BN monolayer are investigated on the basis of first-principles calculations, quantum Born-Oppenheim molecular dynamic simulations (BOMD) and micro-kinetic analysis. We show that CO oxidation on h-BN monolayer support single gold atom prefers an unreported tri-molecular Eley-Rideal (E-R) reaction, where O2 molecule is act...
The CO preferential oxidation (PrOx) is one of the critical steps in hydrogen production and purification for Polymer Electrolyte Membrane Fuel Cell (PEMFC). This reaction was investigated in the presence of excess hydrogen over Cu/CeO2, Pt/CeO2 and Cu-Pt/CeO2 catalysts. The ceria supports was prepared via precipitation method and Cu-Pt/CeO2 catalyst was synthesized by sequential impregnation o...
In this paper, xCuO/CeO2–γAl2O3 nano-catalysts were successfully synthesized by precipitation from an aqueous solution which modified via ultrasonic waves. For characterization of xCuO/CeO2–γAl2O3 samples N2 adsorption results showed that the BET surface area of the CuO/CeO2–γAl2O3, X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive X-rays (EDX dot-mapping) were u...
The influence of external noise on minimalistic models for the catalytic CO oxidation on Ir(111) and Pt(111) is studied by means of the adiabatic elimination technique. Two models, which reproduce the bistable behavior usually observed in CO oxidation on Pt group metal surfaces, are analyzed. The noise is superposed on the fraction of CO in the constant gas flow directed at the surfaces and the...
A single metal atom stabilized on two dimensional materials (such as graphene and h-BN) exhibits extraordinary activity in the oxidation of CO. The oxidation of CO by molecular O2 on a single cobalt atom embedded in a hexagonal boron nitride monolayer (h-BN) is investigated using first-principles calculations with dispersion-correction. It is found that the single Co atom prefers to reside in a...
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