Simultaneous reduction of WCl6 and CCl4 with bismuth metal at 400 degrees C affords a black solid, from which the new cluster [W6CCl18]2- is extracted into aqueous HCl. The cluster is isolated in 34% yield as (Bu4N)2[W6CCl18] and features a metal-metal bonded W6 trigonal prism centered by a carbon atom and surrounded by 12 edge-bridging and 6 terminal chloride ligands. A cyclic voltammogram of ...

Palmitoylation of NMDARs occurs at two distinct cysteine clusters in the carboxyl-terminus of GluN2A and GluN2B subunits that differentially regulates retention in the Golgi apparatus and surface expression of NMDARs. Mutations of palmitoylatable cysteine residues in the membrane-proximal cluster to non-palmitoylatable serines leads to a reduction in the surface expression of recombinant NMDARs...

Peer-to-peer computing is a popular paradigm for different applications that allow direct message passing among peers. The existing P2P search algorithms in MANET (Mobile Ad-hoc Network) are flooding-based search that produces much traffic and network overhead. File searching efficiency of peer-to-peer (P2P) network mainly depends on the reduction of message overhead. This paper deals with a fu...

Biotin synthase catalyzes the insertion of a sulfur atom into the saturated C6 and C9 carbons of dethiobiotin. This reaction has long been presumed to occur through radical chemistry, and recent experimental results suggest that biotin synthase belongs to a family of enzymes that contain an iron-sulfur cluster and reductively cleave S-adenosylmethionine, forming an enzyme or substrate radical, ...

UNLABELLED The L-cluster is an all-iron homolog of nitrogenase cofactors. Driven by europium(II) diethylenetriaminepentaacetate [Eu(II)-DTPA], the isolated L-cluster is capable of ATP-independent reduction of CO and CN(-) to C1 to C4 and C1 to C6 hydrocarbons, respectively. Compared to its cofactor homologs, the L-cluster generates considerably more CH4 from the reduction of CO and CN(-), which...

Diphenylamine (DPA), a known inhibitor of polyene and isoprene biosynthesis, is shown to inhibit flash-activatable electron transfer in photosynthetic membranes of Rhodobacter capsulatus. DPA is specific to the QO site of ubihydroquinone:cytochrome c oxidoreductase, where it inhibits not only reduction of the [2Fe-2S]2+ cluster in the FeS subunit and subsequent cytochrome c reduction but also h...

In this study, we consider the problem of synthesising custom networks-on-chip (NoC) architectures that are optimised for a given application. Both unicast and multicast traffic flows are considered in the input specification. We formulate the joint multicast routing and network design problem using a rip-up and reroute procedure, where each multicast routing step is formulated as a minimum dir...

A better understanding of midlife women’s exercise goals could offer insight into the psychosocial facilitators and barriers to their participation. A random sample of US working women (40–60 years) was taken, and resulted in 262 participants. Cluster analysis identified participants’ most important physical activity goal. A five goal cluster solution was identified: (1) sense of well-being; (2...

In this paper, we propose a static data partitioning scheme for content-based multimedia data retrieval using a heterogeneous cluster system. Multimedia data is represented by unified k-tree structure of kdimensional(k-d) signals proposed in [6]. Each dimension of k-d data is separated into small blocks and then formed into a hierarchical multidimensional tree structure, called a k-tree. The pa...

Text classification is a challenging task due to the large dimensionality of the feature vector. To alleviate this problem, feature reduction techniques are applied for reducing the amount of time and complexity for text classification. In this paper, we propose a novel fuzzy self constructing algorithm for feature clustering. Feature clustering is a feature reduction method which drastically r...