Lamellar gel networks based on mixtures of cetostearyl alcohol and a cationic surfactant, cetyl-trimethylammonium chloride, were studied using combination rheometry optical coherence tomography (OCT) velocimetry. Experiments conducted in stress-controlled rheometer with parallel plate geometry. Each formulation was found to exhibit yield stress thixotropy. The shear start-up behavior response c...

A rotaxane host system containing a novel halogen bonding (XB) 5-iodo-1,2,3-triazole functionalised pyridinium motif, within its axle component, has been prepared via a ring closing metathesis reaction, using chloride as a template. Proton NMR titration experiments, in competitive 1 : 1 CDCl3-CD3OD solvent media, showed the XB rotaxane selectively bound halides over larger, more basic oxoanions...

Cross-linked poly(N-benzyl-4-vinylpyridinium halide) (designated insoluble BVP) was previously reported to capture bacterial cells alive by contact with them. The corresponding linear polymer poly(N-benzyl-4-vinylpyridinium salt) (designated soluble BVP) was found to exhibit antibacterial activity. This soluble pyridinium-type polymer showed strong antibacterial activity against gram-positive b...

Article history: Received on: 31/10/2013 Revised on: 26/11/2013 Accepted on: 07/01/2014 Available online: 20/01/2014 Lactobacillus rhamnosus is known as species that had many benefits in pharmaceutical, dairy food industry. To supply more applications for life, the detection of uronic production of Lactobacillus rhamnosus PN04 was done. After the extracellular components of Lactobacillus rhamno...

A cationic surfactant-selective electrode for sensitive analysis of cationic surfactant has been developed by using a plasticized poly (vinyl chloride) membrane based on nanocomposite cation exchanger polypyrrole zirconium titanium phosphate. The electrode is excellently selective for the cetyl trimethyl ammonium bromide (CTAB) ion over inorganic ions and other cationic surfactants. The membran...

Methacryloxylethyl cetyl ammonium chloride (DMAE-CB) is a polymerizable antibacterial monomer and has been proved as an effective strategy to achieve bioactive bonding with reliable bacterial inhibitory effects. However, the toxicity of DMAE-CB may hamper its wide application in clinical situations. Thus, this study was designed to investigate the toxicity of DMAE-CB and explore the possible pr...

Micelles formed in water from ammonium dodecyl sulfate (AmDS) are characterized using time-resolved fluorescence quenching (TRFQ), electron paramagnetic resonance (EPR), conductivity, Krafft temperature, and density measurements. TRFQ was used to measure the aggregation number, N, and the quenching rate constant of pyrene by dodecylpyridinium chloride, k(Q). N depends only on the concentration ...

OBJECTIVES Cetylpyridinium chloride (CPC), a quaternary ammonium compound, was shown to interact irreversibly with Streptococcus mutans biofilms, leading to a slow diffusion compared with poly(ethylene glycol) (PEG) molecules of similar size. The objective of this work is to determine if the retardation of CPC diffusion and its strong binding to biofilms is caused by interactions between the am...

Understanding and engineering the flow-response of complex and non-Newtonian fluids at a molecular level is a key challenge for their practical utilisation. Here we demonstrate the coupling of microfluidics with small angle neutron scattering (SANS). Microdevices with high neutron transmission (up to 98%), low scattering background (≲10⁻² cm⁻¹), broad solvent compatibility and high pressure tol...