Abstract A sustainable photochemical protocol for the oxidation of alcohols to ketones and carboxylic acids has been developed by using 2,4,6‐triphenylpyrylium tetrafluoroborate (TPPT) as organophotocatalyst molecular oxygen oxidant under visible light irradiation. The key reactive species, superoxide (O 2 •− ) first step from alcohol aldehyde singlet ( 1 O second acid, were generated successfu...

The synthesis of new derivatives 2-[(1,4-dioxo-1-amino-4-arylbutyl-2-en-2-yl)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylic acid is described. Starting 2-{[5-aryl-2-oxofuran-3(2H)-ylidene]amino}thiophene-3-carboxylic acids were obtained by intramolecular cyclisation substituted 4-aryl-4-oxo-2-thienylaminobut-2-enoic in acetic anhydride. New via decyclization reaction acids. structure t...

Carboxylic acids are employed as the vital starting materials in organic synthesis. Various aromatic and aliphatic carboxylic participate electrochemical decarboxylative transformations which CO2 gets liberated generate active carbocation species that reacted with various nucleophiles to produce C−C, C−N, C−O, C−S, C−halogen bonds. L. Tian, Y. Wang et al. discuss recent developments decarboxyla...

A variety of hetero(aromatic) carboxylic acids are shown to undergo decarboxylative homocoupling, mediated by a Pd/Ag system. This novel methodology for the synthesis of symmetrical biaryls avoids the use of haloarenes and organometallic compounds as starting materials.

the 13c chemical shifts for a series of compounds which includes carboxylic acids, aldehydes, ethers, ketones and hydrocarbons were simulated by using the parametric techniques. the observed chemical shifts were related to numerically encoded structural parametes called descriptors. two new electronic descriptors were added to the previous descriptors. ploting of experimental versus calculated ...

A highly efficient and mild palladium-catalyzed decarboxylative cross-coupling of aryl boronic acids and alkynyl carboxylic acids for the synthesis of unsymmetrical substituted alkynes is described for the first time.