نتایج جستجو برای: calix4 arene
تعداد نتایج: 2973 فیلتر نتایج به سال:
In the title compound, C(23)H(21)FN(6)O, the dihedral angle between the fluoro-phenyl and pyrimidinone rings is 75.9 (1)°, and the dihedral angle between the methyl-phenyl and pyrazole rings is 40.3 (1)°. In the crystal structure, weak C-H⋯π(arene) and C-N⋯π(arene) inter-actions and intermolecular C-H⋯N and N-H⋯O hydrogen-bonding inter-actions are present.
η 6 -Arene(iodido-/bromido-aluminato)lanthanoid(III) complexes, [Ln(η -C H 5 Me)(AlI 4 ) 3 ] [ Ln = La ( 1 ), Ce 2 Nd (Gd) ); C Me toluene], -1,3,5)(AlI [Ln Pr 7 8 Sm 9 Gd 10 -1,3,5 mesitylene], and Me)(AlBr 11 12 13 )] were prepared by reactions of aluminium triiodide or tribromide with the corresponding lanthanoid metals 1,2-diiodoethane 1,2-dibromoethane in an arene (toluene mesitylene) solu...
SYNTHESIS OF CALIX[4]ARENES WITH FIXED CONFORMATION AS POTENTIAL INHIBITORS OF FIBRIN POLYMERIZATION
Aim. The purpose of the present study was to develop a method for fixation ‘fixed’ conformation estimation impact calix[4]arene structure on efficacy its anticoagulant activity. This achieved by substitution lower rim C-145 analogue. Methods.Calix[4]arene C-145F (compound 6) obtained in 4 steps starting with Duff reaction. Calix[4]arene methylene-bis-phosphonic ester 3 prepared via addition dii...
We describe the calixarene-cyclodextrin-coupling via click reaction starting from 5,11,17,23-tetra-tert-butyl-25,27-dipropargylether-26,28-hydroxy-calix[4]arene (calix[4]arene-dipropargylether) (2) onto 6I-azido-6I-deoxycyclomaltoheptaose (3) under microwave assisted conditions. The coupling was proven by MALDI-TOF mass spectrometry, ¹H NMR and IR-spectroscopy. The pH dependent supramolecular c...
An amphiphilic calix[4]arene bearing branched 3,4,5-tris(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzamide groups at the upper rim was synthesized and could increase the solubility of naproxen and ibuprofen in water through hydrogen bonding and π-π stacking interactions. The interactions between amphiphilic calix[4]arene and carboxylic acids such as naproxen and ibuprofen could reverse the directio...
The synthesis of a pentadentate ligand with strategically designed fluorinated arene groups in the second coordination sphere of a nonheme iron center is reported. The oxidatively resistant fluorine substituents allow for the trapping and characterization of an Fe(IV)(O) complex at -20 °C. Upon warming of the Fe(IV)(O) complex, an unprecedented arene C-F hydroxylation reaction occurs. Computati...
Nitration of p-tert-butylcalix[n]arene methyl ethers under a variety of reaction conditions has been examined. It has been determined that amongst different nitration procedures adopted (AlCl3/KNO3, HNO3/CH3COOH, HNO3/(CH3CO)2O, cerium(IV) ammonium nitrate/CH3COOH), ipso-nitration with CH3COOH/HNO3 gives best yields of p-nitrocalixarenes and work up conditions. ipso-Nitration of tetramethoxytet...
In the crystal of 2-(4-chloro-phen-yl)-N-(2-iodo-phen-yl)acetamide, C14H11ClINO, mol-ecules are linked by a combination of N-H⋯O and C-H⋯O hydrogen bonds to form a C(4)C(4)[R21(7)] chain of rings and chains of this type are linked by a combination of C-Cl⋯π(arene) and C-I⋯π(arene) inter-actions to form deeply puckered twofold inter-woven sheets. In the crystal of 2-(4-chloro-phen-yl)-N-(pyrazin...
In the title compound, C(56)H(44)Br(4)O(4), the calix[4]arene unit displays the 1,2-alternate conformation with crystallograpically imposed inversion symmetry. The four phen-oxy rings of the calix[4]arene unit are twisted about the mean plane defined by the four methyl-ene C atoms bridging the benzene rings, with dihedral angles of 46.73 (6) and 66.11 (5)°. The dihedral angle between adjacent p...
In the crystal structure of the title compound, C(60)H(70)N(2)O(10)·4CH(3)CN, the calix[4]arene mol-ecule adopts an open-cone conformation with two intra-molecular O-H⋯O hydrogen bonds. The four benzene rings of the calix[4]arene are twisted to the mean plane defined by four methyl-ene C atoms bridging the benzene rings, with dihedral angles ranging from 57.74 (10) to 65.99 (12)°. Two pendant n...
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