Calcium carbonate (CaCO3) in the presence of single-walled carbon nanotube (SWCNT) /fullerodendron supramolecular nanocomposites was crystallized with a CO2 diffusion method under ambient conditions and in aqueous environments to produce monodisperse spherical SWCNT/CaCO3 hybrids with a core-shell structure. The crystals nucleate at the carboxyl groups on the surface of the SWCNT/fullerodendron...

The growth kinetics of calcite crystals are studied in a batch-fluidized-bed crystallizer, which is maintained at a constant pH. The growth experiments are conducted in the metastable region explored as part of this research. The crystal growth rates are e®aluated from the consumption rates of calcium ions, using the cured natural calcite or silica sand as seeding materials. Se®eral operation ®...

We report on atomic force microscopy (AFM) in ambient and liquid environments with the qPlus sensor, a force sensor based on a quartz tuning fork with an all-electrical deflection measurement scheme. Small amplitudes, stiff sensors with bulk diamond tips and high Q values in air and liquid allow to obtain high resolution images. The noise sources in air and liquid are analyzed and compared for ...

Ž . At two caves Clamouse, S France and Ernesto, NE Italy , cave drip and pool waters were collected and sampled at intervals over a 2–3 year period. MgrCa and SrrCa concentration ratios, corrected for marine aerosols, are compared with those of bedrocks and, in some cases, aqueous leachates of soils and weathered bedrocks. Cave waters do not lie along mixing lines between calcite and dolomite ...

Let $D$ be a finite simple digraph with vertex set $V(D)$ and arcset $A(D)$. A twin signed total Roman dominating function (TSTRDF) on thedigraph $D$ is a function $f:V(D)rightarrow{-1,1,2}$ satisfyingthe conditions that (i) $sum_{xin N^-(v)}f(x)ge 1$ and$sum_{xin N^+(v)}f(x)ge 1$ for each $vin V(D)$, where $N^-(v)$(resp. $N^+(v)$) consists of all in-neighbors (resp.out-neighbors) of $v$, and (...

Stable isotope analyses of discrete seasonal layers from a 108-yr annually laminated freeze-core from Baldeggersee, a small, eutrophic lake in central Switzerland, provide information on the climatological and environmental factors, including lake eutrophication, that control oxygen and carbon isotopic composition of epilimnic biologically induced calcite precipitate. During the last 100 yr, Ba...

Biomineralization processes are the subject of numerous investigations. This article gives a review of the study on interactions between the charged polypeptides and the mineral surfaces involved in biomineralization, with an additional kinetic approach. The influence of polypeptides on two types of precipitation processes is discussed: the spontaneous precipitation from supersaturated solution...

BACKGROUND A proposed strategy for immobilizing trace metals in the subsurface is to stimulate calcium carbonate precipitation and incorporate contaminants by co-precipitation. Such an approach will require injecting chemical amendments into the subsurface to generate supersaturated conditions that promote mineral precipitation. However, the formation of reactant mixing zones will create gradie...

Extensive calcite fault cement has resulted from leakage of Santa Barbara basin fluids and hydrocarbons into the Refugio-Carneros fault, a north-bounding structure to the basin. Calcite cements are only found at the end segments of the 24-km (15-mi)-long fault zone, which has less than 150 m (490 ft) of maximum normal offset. The calcite is contemporaneous with fault movement, as evidenced by p...

The study of the carbonate cements in the Permian-Triassic Dalan-Kangan formations resulted in the identification of five stages of calcite and dolomite cementation, which completely or partially occluded pores. Cement types appear to be early isopachous calcite (i; C1-non-luminescence), equant (ii; C2-dull CL), fairly coarse secondary dolomite rhombs (iii; C3-zoning red CL), coarse sparry calc...