Biodegradable aliphatic random copolyesters poly(butylene succinate-co-butylene adipate), PBSA and poly(butylene succinate-co-butylene azelate), PBSAz were synthesized from 1,4 butane diol, succinic acid and adipic acid/azelaic acid through direct melt polycondensation with Titanium Tetra isopropoxide (TTiPO) as a catalyst. These polyesters were characterized by Viscosity measurements, 1H NMR s...

Butane monooxygenase (BMO) from Pseudomonas butanovora has high homology to soluble methane monooxygenase (sMMO), and both oxidize a wide range of hydrocarbons; yet previous studies have not demonstrated methane oxidation by BMO. Studies to understand the basis for this difference were initiated by making single-amino-acid substitutions in the hydroxylase alpha subunit of butane monooxygenase (...

The influence of initial pH on growth and nutrient (total sugars, nitrogen, and phosphorous) consumption by Enterococcus faecium CECT 410 was studied during batch cultures in whey. With these data, two realkalized fed-batch fermentations were developed using different feeding substrates. The shift from homolactic to mixed acid fermentation, the biphasic kinetics observed for cell growth and nit...

The results of an extensive study of desorption in hexane (monolayer and submonolayer) and hexane/butane mixtures initially adsorbed onto the graphite basal plane is presented. Molecular dynamics (MD) simulations are utilized to carry out atomistic simulations at temperatures 300≤T≤700 for all three cases studied. Results from submonolayer and monolayer hexane indicate that the desorption energ...

In the mononuclear title iridium(III) complex, [Ir(C4H8)(C15H22BN6)(C3H9P)], which is based on the [tris-(3,5-dimethyl-pyrazol-1-yl)hydro-borato]iridium moiety, Ir[Tp(Me2)], the Ir(III) atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethyl-phosphane ligand in a modestly distorted octa-hedral coordination environment formed by three facial N, two C and one P atom. The iridi...

A new type of fluorescent sensor has been developed from a perylene based molecule, N,N'-dideoxythymidine-3,4,9,10-perylene-tetracarboxylic diimide (TT-PTCDI); the strong, highly selective binding between the thymine ligand (T) and Hg2+ ion enables efficient sensing of mercury ions based on a fluorescence quenching mechanism, which is primarily caused by metal-coordination induced molecular agg...

From a variety of long simulations of all-atom butane using both stochastic and fully solved molecular dynamics, we have uncovered striking generic behavior that also occurs in one-dimensional systems. We find an apparently universal distribution of transition event durations, as well as a characteristic speed profile along the reaction coordinate. An approximate analytic distribution of event ...

A 29 kDa cysteine protease of Taenia solium metacestodes was purified by Mono Q anion-exchanger and Superose 6 HR gel filtration chromatography. The enzyme was effectively inhibited by cysteine protease inhibitors, such as iodoacetic acid (IAA) and trans-epoxy-succinyl-L-leucyl-amido (4-guanidino) butane (E-64) while inhibitors acting on serine- or metallo-proteases did not affect the enzyme ac...

Diversely sourced degradation products of higher plant lignans were identified in modern and ancient woodrat (Neotoma) middens. The markers indicate extensive chemical modification by intestinal microbial communities of mammals. The observed defunctionalized phenols represent a group of natural products, and their structural elements reveal information about the plant source. The phenols are de...

We present an all atom potential energy function for the simulation of proteins and nucleic acids. This work is an extension of the CH united atom function recently presented by S. J. Weiner et al. (J . Amer. Chem. SOC., 106,765 (1984). The parameters of our function are based on calculations on ethane, propane, n-butane, dimethyl ether, methyl ethyl ether, tetrahydrofuran, imidazole, indole, d...