In the procedure of Schram, Moore, and Bigwood (1) for the determination of the cystine plus cysteine content of a protein, the directions for the concentration of the reaction mixture need to be followed explicitly in order to avoid overoxidation. The addition of a reducing agent to destroy the excess performic acid before the concentration step would seem appropriate if the reductant would ha...

Sea ice is an integral part of the earth’s climate system because it affects planetary albedo, sea-surface salinity, and the atmosphere–ocean exchange of reactive gases and aerosols. Bromine and iodine chemistry is active at polar sea ice margins with the occurrence of bromine explosions and the biological production of organoiodine from sea ice algae. Satellite measurements demonstrate that co...

Two different polymer systems have been studied in regards to their potential for functionalization to introduce new characteristics to the polymer. The first polymer system is a poly(arylene ether) with a truly pendant sulfone group from the monomer 3,5-difluorodiphenylsulfone. The work entails incorporating a bromine moiety onto the monomer for the versatile ability to bring in functional gro...

The chemical behavior of various oligoenes 2 has been studied. The catalytic hydrogenation of diene 3 yielded monoene 4. Triene 7 was hydrogenated to diene 8, monoene 9 and saturated hydrocarbon 10. Bromine addition to 3 and 7 yielded the dibromides 17 and 18, respectively, i.e., the oligoene system has been attacked at its terminal olefinic carbon atoms. Analogously, the higher vinylogs 19 and...

Remote sensing of bromine monoxide (BrO) from the Ozone Monitoring Instrument (OMI) and other satellite instruments opens the possibility to extend our understanding of atmospheric halogen chemistry from local-scale studies to global scales. In the Arctic springtime boundary layer, these bromine monoxide radicals and bromine atoms are known to destroy ozone [1] and oxidize mercury [2], leading ...