Bioengineered spider silk block copolymers were studied to understand the effect of protein chain length and sequence chemistry on the formation of secondary structure and materials assembly. Using a combination of in vitro protein design and assembly studies, we demonstrate that silk block copolymers possessing multiple repetitive units self-assemble into lamellar microstructures. Additionally...

ThFFF with multiple detection enables monitoring the transformation of block copolymers into single chain nanoparticles stabilized by a shell (SCNP-shell). The SCNP-shell are in dynamic equilibrium nanoparticles.

In this paper, we propose a novel block cipher mode of operation, which is known as the counter chain (CC) mode. The proposed CC mode integrates the cipher block chaining (CBC) block cipher mode of operation with the counter (CTR) mode in a consistent fashion. In the CC mode, the confidentiality and authenticity of data are assured by the CBC mode, while speed is achieved through the CTR mode. ...

We report a catalytic system that produces olefin block copolymers with alternating semicrystalline and amorphous segments, achieved by varying the ratio of alpha-olefin to ethylene in the two types of blocks. The system uses a chain shuttling agent to transfer growing chains between two distinct catalysts with different monomer selectivities in a single polymerization reactor. The block copoly...

We propose a new witness encryption based on Subset-Sum which achieves extractable security without relying on obfuscation and is more efficient than the existing ones. Our witness encryption employs multilinear maps of arbitrary order and it is independent of the implementations of multilinear maps. As an application, we construct a new timed-release encryption based on the Bitcoin protocol an...

Photoinduced ordering of disordered block copolymers (BCPs) would provide an on-demand, nonintrusive route for formation of well-ordered nanostructures in arbitrarily defined regions of an otherwise disordered material. Here we achieve this objective using a rapid and simple approach in which photoconversion of an additive blended with the BCP introduces strong interactions between the additive...