The mutual entropic depletion force felt by two solute "big" hard spheres immersed in a binary mixture solvent of nonadditive "small" hard spheres is calculated as a function of the surface-to-surface distance by means of canonical Monte Carlo simulations and through a recently proposed rational-function approximation [R. Fantoni and A. Santos, Phys. Rev. E 84, 041201 (2011)]. Four representati...

A method employing reverse phase high performance liquid chromatography has been developed for the purification of large denatured peptides. The cyanogen bromide fragments of hemoglobin a, 8, and y chains (13 to 91 residues in length) could be separated and recovered in 71 to 95% yields using LiChrosorb C-8 columns and a binary solvent system consisting of 0.013 M trifluoroacetic acid in water ...

−− The aim of this work is to simulate and analyze an extractive distillation process (extractive distillation and recovery columns) for the separation of Tetrahydrofuran (THF)-Water azeotropic mixture using Aspen Plus® and Aspen Split simulators. Calculation of vapor liquid equilibrium of Tetrahydrofuran–Water–Entrainer system was done using the NRTL model, which binary interaction parameters ...

We report Monte Carlo simulations of phase behavior of colloidal suspensions with near-critical binary solvents using effective pair potentials from experiments. At off-critical solvent composition, the calculated phase diagram agrees well with measurements of the experimental system, indicating that many-body effects are limited. Close to the critical composition, however, agreement between ex...

The aggregation of liquid crystal nanodroplets from a homogeneous solution is an important but not well understood step in the preparation of various advanced photonic materials. Here, the authors performed molecular dynamics computer simulations of the formation of liquid crystalline nanodroplets, starting from an isotropic and uniform binary solution of spherical Lennard-Jones (solvent) and e...

Surprising weak assembly behavior has lately been found in binary aqueous solvents containing antagonistic salt. The underlying mechanism is still under debate, particularly the role of ion size asymmetry. Here we use small-angle X-ray scattering to study the effect of ion size asymmetry on the mesoscale ordering in a binary solvent composed of water and 2,6-dimethylpyridine with added symmetri...

The dielectric relaxation time (τ ) of binary mixtures of different molar concentrations of pyridine (C5H5N) and N, Ndimethylacetamide (DMA) in benzene solution has been calculated by using standard microwave techniques and Gopala Krishna's [Trans Farad Soc, 33 (1957) 767.] single frequency (9.875 GHz) concentration variational method at different temperatures (25, 30, 35 and 40°C). It is found...

Spatial confinement of a near-critical medium changes its fluctuation spectrum and modifies the corresponding order parameter distribution, resulting in effective, so-called critical Casimir forces (CCFs) acting on the confining surfaces. These forces are attractive for like boundary conditions of the order parameter at the opposing surfaces of the confinement. For colloidal particles dissolved...

Combinatorial libraries of de novo amino acid sequences can provide a rich source of diversity for the discovery of novel proteins. Randomly generated sequences, however, rarely fold into well ordered protein-like structures. To enhance the quality of a library, diversity must be focused into those regions of sequence space most likely to yield well folded structures. We have constructed focuse...

I use a Landau theory to study the behavior of A – B heteropolymers with disordered sequences immersed in a binary solvent mixture. Segments of type A are preferentially solvated in one type of solvent, and those of type B prefer the other type of solvent. At high temperatures, the behavior is qualitatively the same as that in a single solvent. As the temperature approaches the critical tempera...